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CATALYST FOR HYDROGENATING PLANT OIL AND FATS, PREPARATION METHOD THEREOF AND HYDROGENATION METHOD

机译:加氢植物油脂的催化剂,其制备方法和加氢方法

摘要

FIELD: chemistry.;SUBSTANCE: invention relates to catalysts, particularly used in hydrogenating plant oil and unsaturated fats and can be used in food, perfumery, pharmaceutical, petrochemical and oil-refining industry. Described is a catalyst which contains palladium in amount of 0.1-5.0 wt % and ruthenium in ratio Pd:Ru=1-100 in form of bimetallic particles with size 1-6 nm deposited on a carbon support. Described is a method of preparing the catalyst, involving preliminary combined hydrolysis of palladium (II) and ruthenium (III) chlorides at pH 5-10 and then bringing the precursor into contact with the carbon support and liquid-phase reduction. Described also is a method of hydrogenating triglycerides of plant oil and fats at temperature 80-200°C and pressure 2-15 atm using the catalyst described above.;EFFECT: high efficiency of the method of preparing the catalyst.;2 cl, 5 ex, 2 tbl
机译:技术领域本发明涉及催化剂,特别是用于氢化植物油和不饱和脂肪的催化剂,可用于食品,香料,制药,石化和炼油工业。描述了一种催化剂,该催化剂含有沉积在碳载体上的尺寸为1-6nm的双金属颗粒形式的钯,该钯的含量为0.1-5.0wt%,并且钌的比例为Pd:Ru = 1-100。描述了一种制备催化剂的方法,该方法包括在pH 5-10下钯(II)和氯化钌(III)的氯化物的初步组合水解,然后使前体与碳载体接触并进行液相还原。还描述了使用上述催化剂在80-200℃的温度和2-15atm的压力下氢化植物油脂的甘油三酸酯的方法。效果:该催化剂的制备方法的效率高; 2 cl,5例如,2汤匙

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