首页> 外国专利> TRANSITION METAL-BASED NANOCATALYST, PREPARATION METHOD THEREOF AND USE IN FISCHER-TROPSCH SYNTHESIS REACTIONS

TRANSITION METAL-BASED NANOCATALYST, PREPARATION METHOD THEREOF AND USE IN FISCHER-TROPSCH SYNTHESIS REACTIONS

机译:过渡金属基纳米催化剂及其制备方法及其在费-托合成反应中的应用

摘要

FIELD: chemistry.;SUBSTANCE: invention relates to Fishcher-Tropsch synthesis catalysts. Described is a transition metal-based nanocatalyst for Fischer-Tropsch synthesis, which contains nanoparticles of a transition metal and polymer stabilisers, wherein the transition metal is selected from a group comprising ruthenium, cobalt, nickel, iron and rhodium, or any combination thereof, in which nanoparticles of the transition metal are dispersed in a liquid and the size of the nanoparticles of the transition metal is equal to 1-10 nm. Described is a method of preparing the described nanocatalyst, said method comprising the following steps: mixing and dispersing transition metal salts and polymer stabilisers in liquids, and reducing the transition metal salts with hydrogen in order to obtain a transition metal-based nanocatalyst, where temperature is equal to 100-200°C and concentration of the transition metal salts dissolved in the liquids is equal to 0.0014-0.014 mol/l. Described is a Fischer-Tropsch synthesis process which is carried out using the described nanocatalyst for converting carbon oxide and hydrogen to hydrocarbons.;EFFECT: obtaining an active nanocatalyst for the Fischer-Tropsch synthesis process.;17 cl, 1 tbl, 1 dwg, 10 ex
机译:技术领域本发明涉及Fisher-Tropsch合成催化剂。描述了用于费-托合成的基于过渡金属的纳米催化剂,其包含过渡金属和聚合物稳定剂的纳米粒子,其中过渡金属选自钌,钴,镍,铁和铑,或其任何组合,其中过渡金属的纳米粒子分散在液体中,并且过渡金属的纳米粒子的尺寸等于1-10nm。描述了一种制备所述纳米催化剂的方法,所述方法包括以下步骤:将过渡金属盐和聚合物稳定剂混合并分散在液体中,以及用氢气还原过渡金属盐以获得基于过渡金属的纳米催化剂,在此温度下等于100-200℃,并且溶解在液体中的过渡金属盐的浓度等于0.0014-0.014mol / l。描述了费-托合成工艺,其使用所述纳米催化剂将碳和氢转化为碳氢化合物进行;效果:获得用于费-托合成工艺的活性纳米催化剂; 17 cl,1 tbl,1 dwg, 10前

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