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Method for the separation of hydrocarbons in a plant for producing hydrocarbon from a hydrocarbon-containing element by splitting, comprises compressing and drying the product gas of splitting containing gaseous hydrocarbon material

机译:在通过裂解从含烃元素生产烃的工厂中分离烃的方法,包括压缩和干燥含有气态烃材料的裂解产物气

摘要

The method for the separation of hydrocarbons in a plant for producing hydrocarbon from a hydrocarbon-containing element by splitting (1), comprises compressing and drying the product gas of splitting containing gaseous hydrocarbon material emerging as raw gas (2) and then supplying as feedstock in a separation zone in which the raw gas is separated into a hydrocarbon fraction from hydrocarbon with maximum 3 carbon atoms, and a hydrocarbon fraction from hydrocarbon with 4 carbon atoms. The front end of C 3/C 4-separation consists of C4-absorber (4) and a column. The method for the separation of hydrocarbons in a plant for producing hydrocarbon from a hydrocarbon-containing element by splitting (1), comprises compressing and drying the product gas of splitting containing gaseous hydrocarbon material emerging as raw gas (2) and then supplying as feedstock in a separation zone in which the raw gas is separated into a hydrocarbon fraction from hydrocarbon with maximum 3 carbon atoms, and a hydrocarbon fraction from hydrocarbon with 4 carbon atoms. The front end of C 3/C 4-separation consists of C4-absorber (4) and a column in which hydrocarbons are drawn off with four hydrogen atoms as bottom product. The hydrocarbon fraction is supplied from hydrocarbon with maximum 3 carbon atoms in the separation zone, which consists of first column (12) and a second column. The second column has two separate sections. In the first column, the hydrocarbon fraction from hydrocarbon with maximum 2 carbon atoms is drawn off as main product. The bottom product of the first column is abandoned to the lower section of the second column. The C 4-absorber is operated in a pressure of 11-20 bar and the depropanizer (10) is operated in a pressure of 8-12 bar. The main product of the absorber is supplied to a further compressing zone. The main product of the C 4absorber is supplied over a hydration zone for hydrocarbon with maximum 3 carbon atoms in the first column. The top section of the second column is operated as demethanizer and the lower section of the second column is operated as deethanizer. The two columns are operated on a pressure of 9.5 bar. The main product of the first column is subjected to a deep cooling, in which a fraction is obtained that consists of 90% of methane, and a fraction is obtained that consists of 95% of hydrogen. The condensate obtained in the deep cooling is brought to the top section of the second column. The main product is brought to the top section of the second column in the deep cooling. The bottom product is supplied to the top section of the second column as raw material in a third column in which ethylene is obtained as main product and ethane is obtained as bottom product. The hydrocarbon fraction with 3 carbon atoms is drawn off from sump of the lower section of the second column and is brought as raw material in a fourth column in which propylene is obtained as main product and propane is obtained as bottom product. Cold required in deep cooling is produced with ethylene freezing agent and with recycled gas containing methane and hydrocarbon with 2 hydrocarbon atoms or with a mixture of freezing agent containing hydrocarbon with one, two or three carbon atoms.
机译:在通过裂解(1)从含烃元素生产烃的工厂中分离烃的方法,包括压缩和干燥包含作为原料气出现的气态烃物质的裂解产物气(2),然后作为原料供应在分离区中,其中将原料气从具有最多3个碳原子的烃中分离出烃馏分,并从具有4个碳原子的烃中分离出烃馏分。 C 3 / C 4分离的前端由C4吸收器(4)和一个色谱柱组成。在通过裂解(1)从含烃元素生产烃的工厂中分离烃的方法,包括压缩和干燥包含作为原料气出现的气态烃物质的裂解产物气(2),然后作为原料供应在分离区中,其中将原料气从具有最多3个碳原子的烃中分离出烃馏分,并从具有4个碳原子的烃中分离出烃馏分。 C 3 / C 4分离的前端由C4吸收器(4)和一个塔组成,在该塔中,以四个氢原子作为塔底产物排出烃。烃馏分由分离区中具有最多3个碳原子的烃提供,该分离区由第一塔(12)和第二塔组成。第二列有两个单独的部分。在第一列中,从最大碳数为2的烃中提取出烃馏分作为主要产物。第一列的底部产品被丢弃到第二列的下部。 C 4吸收器的工作压力为11-20 bar,脱丙烷塔(10)的工作压力为8-12 bar。吸收器的主要产品被供应到另一个压缩区。将C 4吸收剂的主要产品通过水合区供应给第一塔中碳原子数最多为3的烃。第二塔的顶部用作脱甲烷塔,第二塔的下部用作脱乙烷塔。两根色谱柱在9.5 bar的压力下运行。对第一塔的主要产物进行深冷,其中获得由90%的甲烷组成的馏分,并且获得由95%的氢组成的馏分。在深冷中获得的冷凝物被带到第二塔的顶部。主要产品在深度冷却中被带到第二塔的顶部。将塔底产物作为第三塔中的原料供应到第二塔的顶部,在第三塔中,以乙烯为主要产物,以乙烷为塔底产物。从第二塔下部的贮槽中抽出具有3个碳原子的烃馏分,并将其作为原料带入第四塔,在第四塔中以丙烯为主要产物,以丙烷为塔底产物。用乙烯冷冻剂和含有甲烷和具有两个碳原子的烃的再循环气体或含有具有一个,两个或三个碳原子的烃的冷冻剂的混合物产生深冷所需的冷。

著录项

  • 公开/公告号DE102009038456A1

    专利类型

  • 公开/公告日2011-03-03

    原文格式PDF

  • 申请/专利权人 LINDE AKTIENGESELLSCHAFT;

    申请/专利号DE20091038456

  • 发明设计人 DUC TUAT PHAM;

    申请日2009-08-21

  • 分类号C07C7/04;C07C7/11;C07C11/06;C07C11/08;

  • 国家 DE

  • 入库时间 2022-08-21 17:47:45

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