PHOSPHINE-PALLADIUM COMPLEX HAVING FERROCENE SKELETON, SUBSTITUTED ACETYLENE POLYMERIZATION INITIATOR, SUBSTITUTED POLYACETYLENE HAVING FUNCTIONAL GROUP INTRODUCED INTO TERMINAL, POLYMER POLYMERIZATION INITIATOR USING THE SAME AND METHOD FOR PRODUCING BLOCK COPOLYMER

摘要

PROBLEM TO BE SOLVED: To provide a new phosphine-palladium complex having a ferrocene skeleton, exhibiting high catalytic activities on the polymerization of a substituted acetylene, and capable of producing a substituted polyacetylene having a narrow molecular weight distribution and functional groups introduced into the terminals.;SOLUTION: The phosphine-palladium complex having the ferrocene skeleton is represented by formula (1) (wherein, R¹ is phenyl or phenoxy; R² is a group selected from a halogen, tosyl, triflate and mesyl; and R³ is substituted aryl).;COPYRIGHT: (C)2012,JPO&INPIT