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METHOD OF IMPROVING THE THERMO-MECHANICAL PROPERTIES OF FIBER-REINFORCED SILICON CARBIDE MATRIX COMPOSITES

机译:改善纤维增强碳化硅基复合材料热力学性能的方法

摘要

A thermal treatment process for improving thermo-mechanical properties of ceramic matrix composite materials such as silicon carbide (SiC) matrix composites is described. The treatment process removes excess silicon and/or other process-related defects from the SiC-based matrix as well as the fiber interfacial coating. This invention can be practiced with minimal strength loss for as-fabricated composites formed from high-strength continuous-length ceramic and carbon-based fibers that are functionally stable to 1600° C. and above. The invention provides a method for significantly improving composite thermal conductivity and creep resistance, and for reducing composite porosity. It has been demonstrated using state-of-the-art 2D woven SiC/SiC composites containing Sylramic-iBN SiC fibers, boron-nitride-based interfacial coatings, and hybrid matrices that are based on SIC formed by chemical vapor infiltration (CVI) and by a combination of CNI, SiC particulate infiltration, polymer infiltration and pyrolysis, and melt infiltration of silicon, silicon-based alloys, and silicides.
机译:描述了一种用于改善陶瓷基复合材料(例如碳化硅(SiC)基复合材料)的热机械性能的热处理工艺。该处理工艺从SiC基基体以及纤维界面涂层中去除了多余的硅和/或其他与工艺相关的缺陷。对于由在功能上稳定至1600℃及以上的高强度连续长度陶瓷和碳基纤维形成的预制复合物,可以以最小的强度损失来实施本发明。本发明提供了一种用于显着提高复合材料的导热性和抗蠕变性并降低复合材料的孔隙率的方法。已使用包含Sylramic-iBN SiC纤维,氮化硼基界面涂层和基于化学气相渗透法(CVI)形成的SIC的混合基体的最新2D编织SiC / SiC复合材料进行了证明通过结合CNI,SiC颗粒渗透,聚合物渗透和热解以及硅,硅基合金和硅化物的熔体渗透来实现。

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