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Cobalt-catalyzed oxidations in volumetrically expanded liquids by compressed gases
Cobalt-catalyzed oxidations in volumetrically expanded liquids by compressed gases
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机译:压缩气体在体积膨胀液体中的钴催化氧化
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摘要
Oxidations of hydrocarbons, cycloalkanes and alkenes, arylalkanes, and a variety of other organic substrates are accomplished by cobalt-N-hydroxysuccinimide co-catalyzed reactions with dioxygen under unusually mild, near ambient conditions of temperature and pressure. The improved safety of the oxidation method and the high yields of product obtained make use of a unique combination of cobalt (II) complexes with N-hydroxysuccinimide. These autoxidation reactions do not have prolonged initiation times. Many of these reactions can be safely performed under normal chemical laboratory conditions and do not require specialized equipment or reagents.
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