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Polyisobutylene-based block anionomers and cationomers and synthesis thereof
Polyisobutylene-based block anionomers and cationomers and synthesis thereof
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机译:聚异丁烯基嵌段阴离子聚合物和阳离子聚合物及其合成
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摘要
Various novel block cationomers comprising polyisobutylene (PIB) and poly(2-dimethylamino)ethyl methacrylate) (PDMAEMA) segments have been synthesized and characterized. The specific targets were various molecular weight diblocks (PDMAEMA+) and triblocks (PDMAEMA+-b-PIB-b-PDMAEMA+) with the PIB blocks in the DPn=50-200 (Mn=3,000-9,000 g/mol) range connected to blocks of PDMAEMA+ cations in the DPn=5-20 range. The overall synthetic strategy for the preparation of these block cationomers comprised four steps: 1) Synthesis by living cationic polymerization of mono- and di-allyltelechelic polyisobutylenes, 2) End group transformation to obtain PIBs fitted with termini capable of mediating the atom transfer radical polymerization (ATRP) of DMAEMA, 3) ATRP of DMAEMA and 4) Quaternization of PDMAEMA to PDMAEMA+I− by CH3I. Kinetic and model experiments provided guidance to develop convenient synthesis methods. The microarchitecture of PIB-PDMAEMA di- and triblock and the corresponding block cationomers were confirmed by 1H NMR and FTIR spectroscopy and solubility studies.
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机译:合成和表征了包括聚异丁烯(PIB)和聚(甲基丙烯酸2-(2-二甲基氨基)乙酯)(PDMAEMA)链段的各种新型嵌段阳离子聚合物。具体的目标是各种分子量的二嵌段(PDMAEMA + Sup>)和三嵌段(PDMAEMA + Sup> -b-PIB-b-PDMAEMA + Sup>)。连接到PDMAEMA + Sup>阳离子嵌段的DP n Sub> = 50-200(M n Sub> = 3,000-9,000 g / mol)范围内的PIB嵌段在DP n Sub> = 5-20范围内。制备这些嵌段阳离子聚合物的整体合成策略包括四个步骤:1)通过活性阳离子聚合合成单-和二-烯丙基螯合聚异丁烯,2)端基转化以获得带有末端的PIB,该末端能够介导原子转移自由基聚合DMAEMA(ATRP),3)DMAEMA ATRP和4)CH 3 Sub> I将PDMAEMA季铵化为PDMAEMA + Sup> I - Sup>。动力学和模型实验为开发方便的合成方法提供了指导。 1 Sup> 1 H NMR,FTIR光谱和溶解度研究证实了PIB-PDMAEMA二嵌段和三嵌段的微结构以及相应的嵌段阳离子聚合物。
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