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USE OF A COMBINATION OF TWO TYPES OF DIFFERENT COUPLING AGENTS AS COUPLING SYSTEM (WHITE FILLER-ELASTOMER) IN RUBBER COMPOSITIONS COMPRISING AN INORGANIC FILLER
USE OF A COMBINATION OF TWO TYPES OF DIFFERENT COUPLING AGENTS AS COUPLING SYSTEM (WHITE FILLER-ELASTOMER) IN RUBBER COMPOSITIONS COMPRISING AN INORGANIC FILLER
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机译:两种不同偶联剂的组合作为偶联系统(白填料-弹性体)在包含无机填料的橡胶组合物中的使用
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摘要
The field of the invention is the use of an effective amount of a polyfunctional coupling system (A) as an inorganic filler-elastomer coupling agent in rubber compositions comprising: (B) at least one rubber-like elastomer natural or synthetic; (C) an inorganic filler as a reinforcing filler; (D) all or part of the other constituents or additives usually used, in particular comprising a vulcanization agent (s); said use being characterized in that + the polyfunctional coupling system (A) consists in the combination of the following ingredients (A1) and (A2): (A1) is at least one coupling agent chosen from functionalized organosilicon compounds of formula (I) below: [(G0) 3 SiO1 / 2] m [(G0) 2 SiO2 / 2] n [G0SiO3 / 2] o [SiO 4/2] p [(G2) a (G1) a '(Z-CO) -N = N-CO-A) SiO (3-a-a ') / 2] q in which the symbols Z, A, G0, G1, G2, a, a', m, n, o, p and q have the meanings given in claim 1; (A2) is at least one coupling agent selected from either "symmetrical" polysulfide silanes or "asymmetric" sulfide silanes; + said polyfunctional coupling system (A) is incorporated into rubber compositions based on isoprenic elastomers.
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机译:本发明的领域是在橡胶组合物中使用有效量的多官能偶联体系(A)作为无机填料-弹性体偶联剂,所述橡胶组合物包含:(B)至少一种天然或合成的橡胶状弹性体; (C)无机填料作为增强填料; (D)全部或部分通常使用的其他成分或添加剂,特别是包括硫化剂;所述用途的特征在于,所述多官能偶联体系(A)由以下成分(A1)和(A2)的组合组成:(A1)为选自以下式(I)的官能化有机硅化合物的至少一种偶联剂。 :[[(G0)3 SiO1 / 2] m [(G0)2 SiO2 / 2] n [G0SiO3 / 2] o [SiO 4/2] p [(G2)a(G1)a'(Z-CO)- N = N-CO-A)SiO(3-aa')/ 2] q,其中符号Z,A,G0,G1,G2,a,a',m,n,o,p和q具有含义在权利要求1中给出; (A2)是选自“对称的”多硫化物硅烷或“不对称的”硫化物硅烷中的至少一种偶联剂; +所述多官能偶联体系(A)被掺入基于异戊二烯弹性体的橡胶组合物中。
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