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Process for preparing low molecular weight olefin (co)polymer and polymerizing catalyst used therefor

机译:低分子量烯烃(共)聚合物的制备方法及其所用的聚合催化剂

摘要

A process for preparing a low molecular weight olefin (co)polymer having a narrow molecular weight distribution with the high productivity, by polymerizing or copolymerizing an olefin in the presence of an olefin polymerizing catalyst comprising (A) a Group 4 transition metal compound represented bythe following general formula (1), and (B) at least one compound selected from (B-1) an organometallic compound, (B-2) an organoaluminum compound, (B-3) anorganoaluminum oxy-compound, and (B-4) a compound which reacts with the Group 4 transition metal compound (A) to form an ion pair, and   a novel Group 4 transition metal compound suitable as an olefin polymerizing catalyst component; (R: hydrogen, hydrocarbon group, or silicon-containing group, M: Ti, Zr or Hf, Y: Group 14 atom, Q: halogen, hydrocarbon group, neutral conjugated or non-conjugated diene, anionic ligand, or neutral ligand which can be coordinated with lone electron pair, n: 2 to 4, j : 1 to 4).
机译:一种通过在包含(A)由下式表示的第4族过渡金属化合物的烯烃聚合催化剂的存在下使烯烃聚合或共聚而以高生产率制备具有窄分子量分布的低分子量烯烃(共)聚合物的方法。下述通式(1)和(B)中的至少一种:选自(B-1)有机金属化合物,(B-2)有机铝化合物,(B-3)有机铝氧化合物和(B-4)的至少一种化合物)与第4族过渡金属化合物(A)反应形成离子对的化合物,和一种适合用作烯烃聚合催化剂组分的新型4族过渡金属化合物。 (R:氢,烃基或含硅基团,M:Ti,Zr或Hf,Y:第14族原子,Q:卤素,烃基,中性共轭或非共轭二烯,阴离子配体或中性配体,其中可以与孤电子对(n:2至4,j:1至4)配合使用。

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