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METHOD FOR THE CATALYTIC OXIDATION OF BENZENE TO PHENOL

机译:苯催化氧化制苯酚的方法

摘要

The invention relates to a method for the catalytic oxidation of benzene to phenol, where the oxidant is hydrogen peroxide and the reaction medium is a mixture of acetonitrile and water, the catalytic oxidation of the benzene being generated by a catalytic system based on copper compounds of formula TpxCu(NCCH3). Said method enables approximately 39% conversions of the starting hydrocarbons with phenol selectivities higher than 92% in processes taking place at 60°C with reaction times of between 2 and 4 hours.
机译:本发明涉及一种将苯催化氧化为苯酚的方法,其中氧化剂为过氧化氢,反应介质为乙腈和水的混合物,苯的催化氧化是由基于铜的铜化合物的催化体系产生的。公式Tp x Cu(NCCH 3 )。所述方法使得在约60℃,反应时间为2至4小时之间发生的过程中,约39%的起始烃转化为苯酚,其选择性高于92%。

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