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SPECIFIC MONOCATIONIC MONOCHROMOPHORIC COMPOUNDS OF HYDRAZONE TYPE COMPRISING A 2-, 4-PYRIDINIUM OR 2-, 4-QUINOLINIUM UNIT, SYNTHESIS THEREOF, DYE COMPOSITIONS CONTAINING THEM, AND METHOD FOR DYEING KERATIN FIBRES
SPECIFIC MONOCATIONIC MONOCHROMOPHORIC COMPOUNDS OF HYDRAZONE TYPE COMPRISING A 2-, 4-PYRIDINIUM OR 2-, 4-QUINOLINIUM UNIT, SYNTHESIS THEREOF, DYE COMPOSITIONS CONTAINING THEM, AND METHOD FOR DYEING KERATIN FIBRES
The present invention relates to monocationic monochromophoric compounds of formulae (I) and/or (II), in which R1 is a hydrogen or an alkyl, phenyl, benzyl, alkylcarbonyl, alkylsulfonyl, aminosulfonyl or aminocarbonyl radical; R5 is an alkyl, phenyl or benzyl; R2 and R3 are a halogen, or an alkyl, aryloxy, arylamino, hydroxyl, alkoxy, (poly)hydroxyalkoxy, alkoxycarbonyl, alkylcarbonyloxy, amino, alkylcarbonylamino, aminocarbonyl, ureido, aminosulfonyl, alkylthio, alkylsulfonylamino, cyano, trifluoromethyl, thio, alkylsulfinyl or alkylsulfonyl radical; R4 is a hydrogen or an alkyl, amino, alkylcarbonylamino, ureido, alkylsulfonylamino, hydroxycarbonyl, alkoxycarbonyl, cyano, phenyl or benzyl radical; R6 and R7 are a hydrogen or an alkyl, alkylcarbonyl, alkoxycarbonyl, alkoxyaryl, aminoaryl, aminocarbonyl or alkylsulfonyl radical, n is between 0 and 4, and n' is between 0 and 4, wherein the electroneutrality of the compounds of formulae (I) and (II) is provided by one or more cosmetically acceptable anions An. It also relates to dye compositions containing said compounds as direct dye, and also to a method for dyeing keratin fibres using this composition and to a multicompartment device. Finally, it relates to methods for synthesizing the compounds of formulae (I) and/or (II).
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机译:本发明涉及式(I)和/或(II)的单阳离子单发色化合物,其中R 1是氢或烷基,苯基,苄基,烷基羰基,烷基磺酰基,氨基磺酰基或氨基羰基。 R5是烷基,苯基或苄基; R2和R3是卤素或烷基,芳氧基,芳基氨基,羟基,烷氧基,(多)羟基烷氧基,烷氧基羰基,烷基羰氧基,氨基,烷基羰基氨基,氨基羰基,脲基,氨基磺酰基,烷硫基,烷基磺酰基氨基,氰基,三氟甲基,硫代,烷基亚磺酰基或烷基磺酰基; R4是氢或烷基,氨基,烷基羰基氨基,脲基,烷基磺酰基氨基,羟基羰基,烷氧羰基,氰基,苯基或苄基; R 6和R 7是氢或烷基,烷基羰基,烷氧基羰基,烷氧基芳基,氨基芳基,氨基羰基或烷基磺酰基基团,n为0至4,且n'为0至4,其中式(I)化合物的电中性(II)由一种或多种化妆品可接受的阴离子An提供。还涉及含有所述化合物作为直接染料的染料组合物,还涉及使用该组合物对角蛋白纤维进行染色的方法以及多隔室装置。最后,本发明涉及合成式(I)和/或(II)的化合物的方法。
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