首页> 外国专利> METHOD FOR REACTING NATURAL GAS TO AROMATICS WHILE ELECTROCHEMICALLY REMOVING HYDROGEN AND ELECTROCHEMICALLY REACTING THE HYDROGEN TO WATER

METHOD FOR REACTING NATURAL GAS TO AROMATICS WHILE ELECTROCHEMICALLY REMOVING HYDROGEN AND ELECTROCHEMICALLY REACTING THE HYDROGEN TO WATER

机译:电化学去除氢气和电化学将氢气转化为水的天然气与芳烃反应的方法

摘要

The invention relates to a process for converting aliphatic hydrocarbons having from 1 to 4 carbon atoms into aromatic hydrocarbons, which comprises the steps: a) reaction of a feed stream E comprising at least one aliphatic hydrocarbon having from 1 to 4 carbon atoms in the presence of a catalyst under nonoxidative conditions to give a product stream P comprising aromatic hydrocarbons and hydrogen and b) electrochemical removal of at least part of the hydrogen formed in the reaction from the product stream P by means of a gastight membrane-electrode assembly comprising at least one selectively proton-conducting membrane and at least one electrode catalyst on each side of the membrane, where at least part of the hydrogen is oxidized to protons over the anode catalyst on the retentate side of the membrane and the protons are, after passing through the membrane on the permeate side, reacted with oxygen to form water over the cathode catalyst, with the oxygen originating from an oxygen-comprising stream O which is brought into contact with the permeate side of the membrane.
机译:本发明涉及将具有1-4个碳原子的脂族烃转化为芳族烃的方法,其包括以下步骤:a)在存在下使包含至少一种具有1-4个碳原子的脂族烃的进料流E反应。在非氧化条件下制备催化剂,以得到包含芳族烃和氢的产物流P,以及b)借助于至少包含至少20%的气密膜-电极组件从产物流P中电化学除去反应中形成的至少一部分氢。在膜的每一侧上具有一个选择性质子传导膜和至少一个电极催化剂,其中至少一部分氢在膜的滞留物侧上的阳极催化剂上被氧化成质子,并且质子在通过渗透侧的膜与氧气反应,在阴极催化剂上形成水,其中氧气来自氧气包含与膜的渗透侧接触的物流O。

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