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VANADIUM DI-NUCLEAR COMPLEX

机译:钒二核络合物

摘要

A method for producing an aromatic compound polymer comprising oxidatively polymerizing one or more of aromatic compound(s) having two or more hydrogen atoms directly connected to aromatic ring(s), in the presence of an oxidizing agent, wherein the method employs a catalyst composed of a transition metal complex or a catalyst prepared from a transition metal complex and an activating agent, and said catalyst has a parameter P defined by the following formula (A) of 0.50 or more, and a parameter Eo defined by the following formula (B) of 0.50 [V] or more: P = Af / Ai (wherein Ai represents an absorbance at an absorption maximum belonging in an absorption band located at the longest wavelength side in an absorption spectrum obtained for a solution containing the catalyst, in a ultraviolet to near-infrared wavelength region from 200 nm to 800 nm, and Af represents an absorbance at the same wavelength applied to the Ai, in an absorption spectrum in the above wavelength region obtained for a solution prepared by adding 3 equivalent of water per mole of the metal contained in the catalyst to the solution), and Eo = Epa + Epc / 2 V (wherein, Epa represents a peak potential at the oxidation side of an oxidation-reduction potential derived from the transition metal contained in the catalyst, at a potential of 0.50 [V] or more based on oxidation-reduction potential of ferrocene/ferrocenium ion measured with a cyclic voltammetry for the solution containing the catalyst, and Epc represents a peak potential at the reduction side corresponding to Epa by the same measurement).
机译:一种制备芳族化合物聚合物的方法,该方法包括在氧化剂的存在下将一种或多种具有两个或多个直接与芳环连接的氢原子的芳族化合物氧化聚合,其中该方法采用由过渡金属配合物或由过渡金属配合物和活化剂制备的催化剂,所述催化剂具有由下式(A)定义的参数P为0.50或更大,并且由下式(B)定义的参数Eo )等于或大于0.50 [V]:P = Af / Ai(其中,Ai表示在从200nm至800nm的紫外至近红外波长区域中,在对于含有催化剂的溶液获得的吸收光谱中,位于位于最长波长侧的吸收带中的最大吸收处的吸光度,和Af表示在上述波长范围内的吸收光谱中,施加到Ai的相同波长处的吸光度,该光谱是通过向溶液中每摩尔催化剂中所含的金属添加3当量的水而制得的溶液的, Epa + Epc / 2 V(其中,Epa表示基于所测二茂铁/二茂铁离子的氧化还原电势,在0.50 [V]或更高的电势下,催化剂中所含过渡金属衍生的氧化还原电势在氧化侧的峰值电势。对于含有催化剂的溶液,用循环伏安法测定,Epc表示在还原侧的峰电位,通过相同的测量对应于Epa。

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