MANUFACTURING METHOD OF DIALKYLCARBONATE CAPABLE OF REMARKABLY IMPROVING YIELD OF DIALKYLCARBONATE AND INCREASING REUSABILITY OF AMBIENT-TEMPERATURE IONIC LIQUID AND CATALYST

摘要

PURPOSE: A manufacturing method of dialkylcarbonate is provided to reduce generation of side product, to manufacture dialkylcarbonate by relatively high yield.;CONSTITUTION: A manufacturing method of dialkylcarbonate comprises a step of reacting urea, C1-3 alkylcarbamate or a mixture thereof, and C1-3 monovalent alcohol under the presence of a catalyst comprising a salt of rare earth metal and transition metal, and ambient-temperature ionic liquid. The salt of the transition metal comprises a salt of a transition metal of group 3 or group 4. The catalyst comprises a salt of Zr, Ce, La or Y. The ionic liquid comprises cation capable of generating hydrogen ions(H+) and hydrophobic anions containing fluorine.;COPYRIGHT KIPO 2013;[Reference numerals] (AA) Urea; (BB) Alcohol; (CC) Solving urea; (DD) First reaction(first reactor); (EE) Second reaction(second reactor); (FF) ROH/alkyl carbamate; (GG) First distillation(first distillation tower); (HH) Ammonia/CO_2; (II) Dialkyl carbonate; (JJ) Deaeration of ammonia(Deaeration part); (KK) Second distillation(second distillation tower); (LL) Dialkyl carbonate; (MM) Membrane separation(membrane separation apparatus); (NN) Third distillation(third distillation tower); (OO) Dialkyl carbonate