首页> 外国专利> PHOTOPOLYMERIC ACRYLIC OLIGOMER-OLIGOMER COMPOSITION, WEAR-RESISTANT COATING ON ORGANIC GLASS FOR GLASING ELEMENTS OF BUILDINGS, STRUCTURES AND VEHICLES BASED THEREON AND METHOD OF PRODUCING WEAR-RESISTANT COATING

PHOTOPOLYMERIC ACRYLIC OLIGOMER-OLIGOMER COMPOSITION, WEAR-RESISTANT COATING ON ORGANIC GLASS FOR GLASING ELEMENTS OF BUILDINGS, STRUCTURES AND VEHICLES BASED THEREON AND METHOD OF PRODUCING WEAR-RESISTANT COATING

机译:光聚合丙烯酸-低聚物-低聚物组成,基于玻璃的建筑,结构和车辆玻璃元件上的有机玻璃上的耐磨涂层及其制备抗磨涂层的方法

摘要

FIELD: chemistry.;SUBSTANCE: disclosed is a novel photopolymer acrylic oligomer-oligomer composition consisting of a bifunctional oligomer, an oligomer with functionality higher than 2, a monomer, a methyl methacrylate oligomer with molecular weight 20000-70000 and a polymerisation initiator, with the following ratio of components in pts.wt: acrylic bifunctional oligomer 15-95; acrylic oligomer with functionality higher than 2 15-70; acrylic monomer 0-25; methyl methacrylate oligomer with molecular weight 20000-70000 5-20; photopolymerisation initiator 0.1-1.0. Disclosed is a wear-resistant coating on organic glass, obtained via photochemically initiated three-dimensional radical polymerisation of the disclosed composition. Disclosed is a method of producing a wear-resistant coating on organic glass, involving a step for preparing a photopolymeric acrylic oligomer-oligomer composition and a step for curing thereof. The technical result is endowing resistance to formation of microcracks during ablation (silver resistance), low shrinkage and high adhesion to a coated substrate obtained via photopolymerisation of acrylic oligomer-oligomer compositions.;EFFECT: invention enables to obtain wear-resistant protective coatings on organic glass with surface hardness close to that of sapphire crystals.;7 cl, 6 tbl, 19 ex
机译:技术领域:公开了一种新型的光敏聚合物丙烯酸低聚物-低聚物组合物,其由双官能低聚物,官能度高于2的低聚物,单体,分子量为20000-70000的甲基丙烯酸甲酯低聚物和聚合引发剂组成,其中pts.wt中组分的以下比例:丙烯酸双官能低聚物15-95;官能度高于2 15-70的丙烯酸低聚物;丙烯酸单体0-25;分子量为20000-70000 5-20的甲基丙烯酸甲酯低聚物;光聚合引发剂0.1-1.0。公开了一种有机玻璃上的耐磨涂层,该涂层通过所公开的组合物的光化学引发的三维自由基聚合而获得。本发明公开了一种在有机玻璃上制备耐磨涂层的方法,该方法包括制备光聚合丙烯酸低聚物-低聚物组合物的步骤及其固化步骤。技术结果是赋予了耐烧蚀过程中形成微裂纹的能力(耐银性),低收缩性和通过丙烯酸低聚物-低聚物组合物的光聚合获得的对涂层基材的高附着力。效果:本发明能够在有机物上获得耐磨保护涂层表面硬度接近蓝宝石晶体的玻璃; 7 cl,6 tbl,19 ex

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