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Method and apparatus for mass spectrometry of a sample with a high utilization

机译:用于高效利用样品进行质谱分析的方法和设备

摘要

Method for measuring the mass spectra with a high degree using a sample, comprising the step of filtering the mass precursor ions of the first group from the mass spectrum with a mass to charge ratio within a predetermined range of the first. Precursor ions of one type, are fragmented then selectively at least the precursor ion in the first group. Fragment mass spectrum of the first precursor ions are fragmented precursor ions in the first group is measured, the precursor ions of other mass-to-charge ratio within a predetermined range of the first is held in the other hand. Precursor ion of the second group with a mass to charge ratio within a predetermined range of the second mass filter is from the mass spectrum. In the precursor ions of a second group of precursor ions of one type is fragmented at least selectively. Fragment mass spectrum of the second precursor ions are fragmented precursor ions in the second group is then measured.
机译:一种使用样品高度测量质谱的方法,其包括以下步骤:以质荷比在第一组的预定范围内从质谱中过滤出第一组的质量前体离子。将一种类型的前体离子破碎,然后至少在第一组中至少选择性地选择前体离子。第一前驱体离子的碎片质谱是测量第一组中的碎片前驱体离子,另一方面保持其在预定范围内的其他质荷比的前驱体离子。质荷比在第二质量过滤器的预定范围内的第二组前体离子来自质谱。在第二类型的前体离子中,一种类型的前体离子被至少选择性地分裂。第二前体离子的碎片质谱是第二组中破碎的前体离子,然后进行测量。

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