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Mesoporous silica particles of core-shell structure

机译:核-壳结构的介孔二氧化硅颗粒

摘要

PPROBLEM TO BE SOLVED: To provide mesoporous silica particles of core-shell structure of which the shell comprises a silicon compound having an organic group and has mesopore structure having an average pore diameter of ≤8 nm, and a method for efficiently producing the same. PSOLUTION: [1] In the mesoporous silica particles of core-shell structure of which the shell has mesopore structure, the shell has an average thickness of 5-700 nm, the particles have an average particle diameter of 0.05-10 μm, the shell comprises a silicon compound having an organic group and includes a water-insoluble material (a) within the same, and the mesopore has an average pore diameter of 1-8 nm. [2] The method for producing such mesoporous silica particles of core-shell structure comprises: preparing a dispersion containing a water-insoluble material, a quaternary ammonium salt and a silica source having an organic group and forming a silanol compound upon hydrolysis; stirring the dispersion at 10-100°C to deposit a complex including the quaternary ammonium salt and silica; and removing the quaternary ammonium salt from the complex. PCOPYRIGHT: (C)2010,JPO&INPIT
机译:解决的问题:提供一种核-壳结构的中孔二氧化硅颗粒,其中该壳包含具有有机基团的硅化合物并且具有平均孔径为±8 nm的中孔结构,并且提供了一种有效的方法生产相同的。

解决方案:[1]在其中壳具有中孔结构的核-壳结构的介孔二氧化硅颗粒中,壳的平均厚度为5-700 nm,颗粒的平均粒径为0.05-10μ ;壳,包括具有有机基团的硅化合物,并且在壳内包括水不溶性材料(a),中孔的平均孔径为1-8nm。 [2]这种核-壳结构的介孔二氧化硅颗粒的制备方法包括:制备含有水不溶性材料,季铵盐和具有有机基团的二氧化硅源的分散体,并在水解时形成硅烷醇化合物。在10-100℃下搅拌该分散体以沉积包括季铵盐和二氧化硅的复合物;并从该配合物中除去季铵盐。

版权:(C)2010,日本特许厅&INPIT

著录项

  • 公开/公告号JP5291980B2

    专利类型

  • 公开/公告日2013-09-18

    原文格式PDF

  • 申请/专利权人 花王株式会社;

    申请/专利号JP20080115172

  • 申请日2008-04-25

  • 分类号C01B37/00;C01B33/18;C08K7/26;C08L101/00;

  • 国家 JP

  • 入库时间 2022-08-21 16:58:43

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