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Polypropylene heat-shrinkable film for a resin composition, and a polypropylene heat-shrinkable film using the same and use thereof

机译:用于树脂组合物的聚丙烯热收缩膜,以及使用该膜的聚丙烯热收缩膜及其用途

摘要

PROBLEM TO BE SOLVED: To provide a heat shrinking film for a PET bottle having a low specific gravity using a small amount of an alicyclic hydrocarbon resin, wherein transparency, gloss and low heat shrinking property are excellent.;SOLUTION: The resin composition comprises (A) 50-95 wt.% of a propylene-ethylene block copolymer and (B) 50-5 wt.% of an alicyclic hydrocarbon resin, and (A) satisfies (A-i) to (A-iii) and (B) satisfies (B-i). In a 1st process, 30-95 wt.% of only propylene or a propylene-ethylene random copolymer ingredient (A1) having ≤7 wt.% ethylene content and in a 2nd process 70-5 wt.% of a propylene-ethylene random copolymer ingredient (A2) containing ethylene in an amount of 3-20 wt.% more than the ingredient (A1) are polymerized step-by-step using a metallocene catalyst (A-i), whereby there is obtained a propylene-ethylene block copolymer having an MFR of 0.1-30 g/10 min. (A-ii) and having a single peak not higher than 0°C in tanδ (A-iii) and having a softening point of 110-160°C (B-i).;COPYRIGHT: (C)2007,JPO&INPIT
机译:解决的问题:提供一种使用少量脂环烃树脂的低比重的PET瓶用热收缩膜,其中透明性,光泽和低热收缩性优异。 A)50-95 wt。%的丙烯-乙烯嵌段共聚物和(B)50-5 wt。%的脂环族烃树脂,并且(A)满足(Ai)至(A-iii)和(B) (双)。在第一方法中,仅30-95重量%的丙烯或具有≤7重量%乙烯含量的丙烯-乙烯无规共聚物成分(A1)在第二方法中,仅70-5重量%的丙烯-乙烯使用茂金属催化剂(Ai)使含乙烯量比成分(A1)多3-20重量%的无规共聚物成分(A2)逐步聚合,从而获得丙烯-乙烯嵌段共聚物。 MFR为0.1-30g / 10min。 (A-ii)并且具有在tanδ中不高于0℃的单个峰。 (A-iii)的软化点为110-16°C(B-i)。;版权所有:(C)2007,JPO&INPIT

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