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Polyolefin resins for stabilizing and stabilized polyolefin resin composition

机译:用于稳定和稳定聚烯烃树脂组合物的聚烯烃树脂

摘要

Disclosed is a stabilizer capable of giving a high degree of thermal stability to a polypropylene resin (PP resin). Also disclosed is a PP resin composition to which the stabilizer is added having a high degree of stability. Specifically disclosed is a stabilizer containing a copolymer (A) which is obtained by polymerizing an unsaturated monomer mixture composed of 1 to 50 parts by mass of an ethylenically unsaturated monomer (a) represented by the following general formula (I) and having a piperidyl group in a molecule, 50 to 99 parts by mass of at least one monomer (b) selected from isobutyl methacrylate, an alkyl (meth)acrylate having an alkyl group with 6 to13 carbon atoms, and an aromatic vinyl monomer, and 0 to 20 parts by mass of an ethylenically unsaturated monomer (c) other than the monomers (a) and (b), with the proviso that the total of the monomers (a), (b), and (c) is 100 parts by mass: wherein R 1 represents a hydrogen atom or an alkyl group having 1 to 2 carbon atoms, X represents an oxygen atom or an imino group, Y represents a hydrogen atom or an alkyl or alkoxyl group each having 1 to 20 carbon atoms, and Z represents a hydrogen atom or a cyano group.
机译:公开了一种能够赋予聚丙烯树脂(PP树脂)高度的热稳定性的稳定剂。还公开了添加了具有高稳定性的稳定剂的PP树脂组合物。具体公开了一种稳定剂,其包含通过使由以下通式(I)表示的1〜50质量份的烯键式不饱和单体(a)构成的不饱和单体混合物聚合而得到的共聚物(A)。 50〜99质量份的选自甲基丙烯酸异丁酯,具有碳原子数6〜13的烷基的(甲基)丙烯酸烷基酯和芳香族乙烯基单体中的至少一种单体(b)为50〜99质量份。单体(a)和(b)以外的烯属不饱和单体(c),以单体(a),(b)和(c)的总量为100质量份为前提:其中R 1代表氢原子或具有1-2个碳原子的烷基,X代表氧原子或亚氨基,Y代表氢原子或各自具有1-20个碳原子的烷基或烷氧基,Z代表氢原子或氰基。

著录项

  • 公开/公告号JP5274025B2

    专利类型

  • 公开/公告日2013-08-28

    原文格式PDF

  • 申请/专利权人 三菱レイヨン株式会社;

    申请/专利号JP20070557677

  • 发明设计人 木浦 正明;椋田 貴寛;

    申请日2007-11-22

  • 分类号C08L23/00;C08F220/34;C08L33/14;C08K5/18;

  • 国家 JP

  • 入库时间 2022-08-21 16:56:26

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