Production method of the polymerizable spherical transition metal complexes, and a method of manufacturing the spherical transition metal complex

摘要

It is formed from a bidentate organic ligand and the present invention relates transition metal atom and are those having a substituent with a polymerizable moiety at the terminal, the bidentate organic ligand wherein said substituent There polymerizable globular transition metal complex having a shell of hollow formed by formed to be oriented to the interior of a shell of the hollow sphere transition metal complex comprising the polymerizable groups are polymerized in the shell of the hollow of the complex, and the I to provide a process for the production. A spherical transition metal complex having a shell of SOLUTION hollow, a transition metal atom, (. Represents an integer of 6~60 a can) bidentate organic high for 2a pieces shell of the hollow is a number It is formed from a ligand, a bidentate organic ligand wherein, and are those having a substituent having a polymerizable group moiety of at least one or more ends, the substituent is oriented in the interior of a shell of hollow polymerizable globular transition metal complex characterized in that it is formed to be spherical transition metal complex comprising the polymerizable moiety is polymerized in the shell of the hollow of the complex, and a manufacturing method thereof. None [Selection Figure]