首页> 外国专利> Stabilized adhesive composition comprising highly soluble, red-shifted, light-stable benzotriazole UV absorbers and laminated articles derived therefrom

Stabilized adhesive composition comprising highly soluble, red-shifted, light-stable benzotriazole UV absorbers and laminated articles derived therefrom

机译:稳定的粘合剂组合物,包括高溶解度,红移的,光稳定的苯并三唑紫外线吸收剂和由其衍生的层压制品

摘要

Adhesive compositions are rendered stable against degradation caused by ultraviolet light through the incorporation of selected highly soluble, red-shifted, photostable benzotriazole UV absorbers which absorb light strongly in the 350 to 400 nm range. Also suitable are 2-(2-hydroxy-3- alpha -cumyl-5-tert-octylphenyl)-2H-benzotriazole and 2-(2-hydroxy-3- alpha -cumyl-5-tert-butylphenyl)-2H-benzotriazole in combination with the red shifted benzotriazoles. A further subject of the invention are novel asymmetrical bisbenzotriazoles of formula (IIIc) where G2' is perfluoroalkyl of 1 to 12 carbon atoms, preferably CF3, and where G2 does not contain said group are red-shifted and due to the asymmetry are particularly soluble and useful in a host of applications including automotive coatings, thermoplastics and especially in adhesive compositions, themselves useful in solar panels and other laminate structures. All these UV absorbers exhibit excellent photostability and are highly soluble in adhesive formulations. The laminated articles derived from these compositions include, for example, solar control films, films and glazings, UV absorbing glasses and glass coatings, windscreens, retroreflective sheetings and signs, solar reflectors, optical films and the like.
机译:通过掺入选定的高度可溶的,红移的,光稳定的苯并三唑紫外线吸收剂,使粘合剂组合物对由紫外线引起的降解稳定,该吸收剂可强烈吸收350至400 nm的光。同样合适的是2-(2-羟基-3-α-枯基-5-叔辛基苯基)-2H-苯并三唑和2-(2-羟基-3-α-枯基-5-叔丁基苯基)-2H-苯并三唑与红移苯并三唑结合使用。本发明的另一个主题是式(IIIc)的新型不对称双苯并三唑,其中G 2'是具有1至12个碳原子的全氟烷基,优选CF 3,并且其中G 2不含所述基团是红移的,并且由于不对称性特别可溶。并且可用于包括汽车涂料,热塑性塑料在内的许多应用,尤其是可用于太阳能电池板和其他层压结构的粘合剂组合物。所有这些紫外线吸收剂均表现出出色的光稳定性,并高度溶于粘合剂配方。衍生自这些组合物的层压制品包括例如日光控制膜,膜和玻璃,紫外线吸收玻璃和玻璃涂层,挡风玻璃,逆反射片和标志,日光反射器,光学膜等。

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