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Method for producing selectively chemically modified carbon nanotubes

机译:选择性化学修饰的碳纳米管的生产方法

摘要

Disclosed is a novel method for the selective molecular conversion of raw material carbon nanotubes containing a mixture of metallic carbon nanotubes and semiconductive carbon nanotubes in a manner that is based on the electrical properties or diameter of the carbon nanotubes. The present invention causes a photoreaction of raw material carbon nanotubes containing a mixture of metallic carbon nanotubes and semiconductive carbon nanotubes with a disulfide or a sulfide of the following formula (I) or (II) (wherein R 1 and R 2 each independently represent a hydrocarbon group that may have a substituent) in an organic solvent that contains the raw material carbon nanotubes and the disulfide of the formula (I) or the sulfide of the formula (II), so as to selectively functionalize the metallic carbon nanotubes, or functionalize the carbon nanotubes diameter selectively.
机译:本发明公开了一种新颖的方法,该方法以基于碳纳米管的电学性质或直径的方式选择性地转化包含金属碳纳米管和半导体碳纳米管的混合物的原料碳纳米管。本发明使包含金属碳纳米管和半导体碳纳米管的混合物的原料碳纳米管与下式(I)或(II)的二硫化物或硫化物发生光反应。(其中R 1和R 2各自独立地表示可以具有取代基的烃基)在含有原料碳纳米管和式(I)的二硫化物或式(II)的硫化物的有机溶剂中,选择性地官能化金属碳纳米管,或选择性地官能化碳纳米管直径。

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