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Polymer containing thiophene unit and thienylenevinylene unit, and organic field effect transistor and organic solar cell containing the polymer

机译:包含噻吩单元和噻吩亚乙烯基单元的聚合物,以及包含该聚合物的有机场效应晶体管和有机太阳能电池

摘要

Provided are a polymer containing a thiophene unit and a thienylenevinylene unit, and an organic field effect transistor and an organic solar cell containing the polymer. The film may be formed by coating a substrate with a polymer containing a thiophene unit and a thienylenevinylene unit using a solution process. Therefore, the production cost may be reduced and a large-scale device may be suitably manufactured since there is no need for an expensive vacuum system to form films. Also, the polymer according to one embodiment of the present invention containing a thiophene unit and a thienylenevinylene unit has very excellent flatness since the thiophene unit is continuously coupled with a vinyl group having excellent flatness. Therefore, the polymer may be useful in further improving the charge mobility since it has high crystallinity caused by the improved ordering property between molecules. Such crystallinity may be further improved by the heat treatment. In addition, the organic compound according to one embodiment of the present invention containing a thienylenevinylene unit may have high oxidative stability because of its high ionization energy.
机译:提供一种包含噻吩单元和噻吩亚乙烯基单元的聚合物,以及包含该聚合物的有机场效应晶体管和有机太阳能电池。可以通过使用溶液法用含有噻吩单元和噻吩亚乙烯基单元的聚合物涂布基板来形成膜。因此,由于不需要用于形成膜的昂贵的真空系统,因此可以降低生产成本并且可以适当地制造大型装置。同样,根据本发明的一个实施方案的包含噻吩单元和噻吩亚乙烯基单元的聚合物具有非常优异的平坦度,这是因为噻吩单元与具有优异平坦度的乙烯基连续偶联。因此,该聚合物由于具有改善的分子间有序性而具有高结晶度,因此可用于进一步改善电荷迁移率。通过热处理可以进一步改善这种结晶度。另外,根据本发明的一个实施方式的包含亚噻吩基亚乙烯基单元的有机化合物由于其高的电离能而可以具有高的氧化稳定性。

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