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Producing Ethanol Using Two Different Streams From Acetic Acid Carbonylation Process

机译:用两种不同的乙酸羰基化工艺生产乙醇

摘要

This invention relates to processes for producing ethanol from at least two different streams obtained by carbonylating methanol. The process comprises the steps of reacting carbon monoxide with at least one reactant in a first reactor containing a reaction medium to produce a reaction solution comprising acetic acid, wherein the at least one reactant is selected from the group consisting of methanol, methyl acetate, methyl formate, dimethyl ether and mixtures thereof and wherein the reaction medium comprises water, acetic acid, methyl iodide, and a first catalyst, purifying the reaction solution to yield an acetic acid product stream and at least one derivative stream, introducing the acetic acid product stream and the at least one derivative stream into a second reactor in the presence of a second catalyst to form a crude ethanol product, and recovering ethanol from the crude ethanol product.
机译:本发明涉及由至少两种通过甲醇羰基化获得的不同物流生产乙醇的方法。该方法包括使一氧化碳与至少一种反应物在包含反应介质的第一反应器中反应以产生包含乙酸的反应溶液的步骤,其中至少一种反应物选自甲醇,乙酸甲酯,甲基甲酸酯,二甲醚及其混合物,其中反应介质包含水,乙酸,碘甲烷和第一催化剂,纯化反应溶液以产生乙酸产物流和至少一种衍生物流,引入乙酸产物流在第二催化剂的存在下,将至少一种衍生物流进第二反应器以形成粗乙醇产物,并从粗乙醇产物中回收乙醇。

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