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4, 4′ disubstituted 4H-cyclopentadithiophene and new methods for synthesizing the same

机译:4,4'二取代的4H-环戊二噻吩及其合成新方法

摘要

The present preferred embodiments relate to a method for the synthesis of a compound having the following general formula:; embedded image the method comprising the step of reacting, in presence of a diprotic acid having a negative pKa, a compound having the general formula:; embedded image wherein R1 and R2 are organic groups and wherein X and Y are independently selected from the group consisting of hydrogen, chloro, bromo, iodo, boronic acid, boronate esters, borane, pseudohalogen and organotin. It further relates to compounds so obtained and to compounds resulting from the ring closure of compound (II).
机译:本发明的优选实施方案涉及具有以下通式的化合物的合成方法: “嵌入式图像” 该方法包括以下步骤:在具有负pKa的二丙酸存在下,使具有以下通式的化合物反应:; “嵌入式图像” 其中R 1 和R 2 是有机基团,并且其中X和Y独立地选自氢,氯,溴,碘,硼酸,硼酸酯,硼烷,假卤素和有机锡。它还涉及如此获得的化合物以及由化合物(II)的闭环产生的化合物。

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