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Process for Making Ethylene Interpolymers and Interpolymers Made Thereby, and Compositions and Electrical Devices Containing Such Interpolymers

机译:制备乙烯互聚物和由此制得的互聚物的方法,以及含有这种互聚物的组合物和电气设备

摘要

The invention relates to a continuous polymerization process for preparing a random ethylene interpolymer which comprises: (A) polymerizing ethylene, and an α-olefin comonomer selected from propylene and/or 1-butene, and mixtures thereof, under continuous random polymerization conditions in the presence of single site catalyst system employing an ionic activator having cyclic ligands shielding a central charge bearing atom, at a temperature of 140° C. to 250° C. at a conversion of ethylene of 80 to 99% and a comonomer conversion of from at least 20%; and (B) devolatilizing the polymer to provide an ethylene copolymer having a density of from 0.85 to 0.92 g/cm3, an MI of from 0.01 to 100 g/10 min and an I21/I2 of from 30 to 400.
机译:本发明涉及一种用于制备无规乙烯互聚物的连续聚合方法,该方法包括:(A)在连续无规聚合条件下,在乙烯的连续聚合条件下,聚合乙烯和选自丙烯和/或1-丁烯的α-烯烃共聚单体及其混合物。存在单点催化剂体系,该体系采用离子活化剂,该离子活化剂在140°C至250°C的温度下,在80%至99%的乙烯转化率下,在200℃至5%的共聚单体转化率下,具有屏蔽中心带电荷原子的环状配体。至少20%; (B)使聚合物脱挥发分以提供密度为0.85至0.92g / cm 3 ,MI为0.01至100g / 10min和I 21的乙烯共聚物。 / I 2 从30到400。

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