The field of this invention relates to supramolecular functional materials, particularly to coordination networks, more particularly to coordination polymers, more particularly to metal based one-dimensional coordination polymers. The metal based one-dimensional coordination polymers comprises a repeat unit [L1-M-L2]n where L1 and L2 are one of a plurality of carboxylate ligands and L1 can be the same as L2, M is a metal, particularly a transition metal, and n is an integer from 1 to infinity. The metal based one-dimensional coordination polymers display one or more physico-chemical properties giving at least one functionality to the supramolecular material. Furthermore, a method of forming the metal based one-dimensional coordination polymers is provided by a chemical reaction between said organic ligand and said metal where said method comprises at least one selectable chemical reaction condition from the group comprising: volume of reaction vessel, material composition of reaction vessel, temperature, pressure, humidity and gas defining an atmosphere inside reaction vessel.
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机译:本发明的领域涉及超分子功能材料,尤其涉及配位网络,更具体地涉及配位聚合物,更具体地涉及基于金属的一维配位聚合物。金属基一维配位聚合物包含重复单元[L 1 Sub> -ML 2 Sub>] n Sub>,其中L 1 Sub >并且L 2 Sub>是多个羧酸盐配体中的一种,并且L 1 Sub>可以与L 2 Sub>相同,M是金属,特别是金属过渡金属,n是1到无穷大的整数。基于金属的一维配位聚合物显示出一种或多种物理化学性质,赋予超分子材料至少一种功能。此外,通过所述有机配体与所述金属之间的化学反应提供了一种形成金属基一维配位聚合物的方法,其中所述方法包括选自以下的至少一种可选化学反应条件:反应容器的体积,材料组成反应容器的温度,压力,湿度和气体的变化定义了反应容器内的气氛。
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