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method for obtaining poly (methyl methacrylate) using nickel complex and application of complex nickel for poly (methyl methacrylate)

机译:镍配合物获得聚(甲基丙烯酸甲酯)的方法和配合物镍在聚(甲基丙烯酸甲酯)中的应用

摘要

method for obtaining poly (methyl methacrylate) and methyl methacrylate using nickel catalyst, is that the methyl methacrylate is subjected to polymerization reaction for poly (methyl methacrylate) in the presence of commercial alumoksanu methyl in toluene and in the presence of katalizat environment ora nickel of general formula 1, where x is cl or br,r and r1 is h or nierozgau0142u0119zionu0105 saturated or insatiable alkilowu0105 c1 - c3 group or - c (ch3) 2ch2ch = ch2, and if r1 is h, r is h or nierozgau0142u0119zionu0105 saturated or insatiable group alkilowu0105 c1 to c3 and if r1 is - c (ch3) 2ch2ch = ch2 is r1 = r and ar means 2,4,6 - trimetylofenyl or 2,6 - diizopropylofenyl.the invention also includes the application of nickel catalyst of the general formula 1, where x is cl or br, r is h or nierozgau0142u0119zionu0105 saturated or insatiable group alkilowu0105 c1 - c3, r1 is h and ar means the 2,4,6 - trimetylofenyl or 2,6 - diizopropylofenyl for poly (metakr ylanu methyl) with methyl methacrylate in the presence of alumoksanu methyl.
机译:镍催化剂获得聚(甲基丙烯酸甲酯)和甲基丙烯酸甲酯的方法,是在商业​​铝矾土甲基存在下,在甲苯中,在钾碱金属或镍的存在下,使甲基丙烯酸甲酯进行聚甲基丙烯酸甲酯的聚合反应。通式1,其中x是cl或br,r,r1是h或nierozga u0142 u0119zion u0105 c1-c3基团或-c(ch3)2ch2ch = ch2,并且如果r1是h, r为h或nierozga u0142 u0119zion u0105饱和或不饱和基Alkilow u0105 c1至c3,并且如果r1为-c(ch3)2ch2ch = ch2为r1 = r且ar表示2,4,6-三苯甲基甲烯基或2, 6-二咪唑基丙基。本发明还包括通式1的镍催化剂的应用,其中x是cl或br,r是h或Ni 2 O 3饱和或不饱和基Al基low u0105 c1-c3,r1是h和ar表示对于聚(metakr yla在甲基铝的存在下,用甲基丙烯酸甲酯。

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