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Process for the production of alkylene carbonate and alkylene carbonate using the thus produced in the manufacture of alkane diol and a dialkyl carbonate

机译:在链烷二醇和碳酸二烷基酯的生产中使用如此生产的方法生产碳酸亚烷基酯和碳酸亚烷基酯的方法

摘要

The process for producing an alkylene carbonate by reacting an alkylene oxide with dióxidode carbon in the presence of a phosphonium catalyst in which process (a) the alkylene oxide, carbon dioxide and the phosphonium catalyst are continuously introduced in unazona reaction of a product stream containing alkylene carbonate and elcatalizador phosphonium used it is removed, (b) alkylene carbonate and a stream containing the catalyst used phosphonium separated from lacorriente product, (c ) alkylene carbonate, separated in step (b), is recovered as product, (d) at least part of the stream containing the catalyst used phosphonium subjected to purification to obtain phosphonium catalyst purified, wherein part of the stream containing phosphonium catalizadorde used that is purified, is subjected to distillation at a distillation temperature ranging from 200 ° C 50a and at a pressure n for the distillation of 0.1 to 0.0001 bar (10 0,01 kPa), and (e) purified phosphonium catalyst is recycled to the reaction zone.
机译:在a催化剂的存在下,通过使环氧烷与二氧杂环丙烷碳反应来生产碳酸亚烷基酯的方法,其中将方法(a)将环氧烷,二氧化碳和phospho催化剂连续地引入到含亚烷基的产物流的重氮反应中除去所用的碳酸根和Elcatalizador nium,(b)碳酸亚烷基酯和从拉考林特产物中分离出的含有用过的phospho的料流,(c)步骤(b)中分离出的碳酸亚烷基酯,作为产物回收,(d)至少将包含所用催化剂的used的部分物流进行纯化以获得纯化的phospho催化剂,其中将所纯化的所用含cat的催化剂的部分物流在200°C 50a的蒸馏温度和n蒸馏0.1至0.0001 bar(10 0,01 kPa),(e)将纯化的phospho催化剂循环到o反应区。

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