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PROCESS FOR PRODUCING A METHANATION CATALYST AND A PROCESS FOR THE METHANATION OF SYNTHESIS GAS

机译:制备甲烷化催化剂的方法和合成气的甲烷化方法

摘要

The present invention relates to a process for producing a catalyst for carrying out methanation reactions. The production of the catalyst is based on contacting of a hydrotaicite-comprising starting material with a fusible metal salt. The compounds brought into contact with one another are intimately mixed, thermally treated so that the metal salt fraction melts and subsequently subjected to a low-temperature calcination step and a high-temperature calcination step. The metal salt melt comprises at least one metal selected from the group consisting of K, La, Fe, Co, Ni, Cu and Ce, preferably Ni. The metal salt melt more preferably comprises/contains nickel nitrate hexahydrate. The hydrotaicite-comprising starting material is preferably hydrotaicite or a hydrotalcite-like compound as starting material, and the hydrotaicite-comprising starting material preferably comprises magnesium and aluminum as metal species. The catalyst of the invention is preferably used for carrying out methanation reactions at elevated pressures (from 10 to 50 bar) and elevated temperatures.
机译:本发明涉及生产用于进行甲烷化反应的催化剂的方法。催化剂的生产基于含水滑石的起始原料与可熔金属盐的接触。将彼此接触的化合物充分混合,进行热处理,以使金属盐级分熔化,然后进行低温煅烧步骤和高温煅烧步骤。金属盐熔体包含选自由K,La,Fe,Co,Ni,Cu和Ce组成的组中的至少一种金属,优选为Ni。金属盐熔体更优选包含/包含硝酸镍六水合物。包含水滑石的起始原料优选为水滑石或类水滑石化合物作为起始原料,并且包含水滑石的起始原料优选包含镁和铝作为金属物质。本发明的催化剂优选用于在升高的压力(10至50巴)和升高的温度下进行甲烷化反应。

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