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WATER-AND-OIL REPELLANT COMPOSITION, FUNCTIONAL TEXTILE PRODUCT, AND PRODUCTION METHOD FOR FUNCTIONAL TEXTILE PRODUCT

机译:水和油排斥剂组成,功能性纺织品产品以及功能性纺织品产品的生产方法

摘要

The water-and-oil repellant composition of the invention including an aqueous dispersion of a pyrazole blocked hydrophobic polyisocyanate containing a pyrazole blocked hydrophobic polyisocyanate represented by the following formula (I) and a non-ionic surface active agent, and a water-and-oil repellant component having a perfluoroalkyl group with 6 carbon atoms or less is provided:        R (-NH-CO-Z)m     (I)[in the formula (I), m represents an integer of 2 or more; R represents a residue after an "m" number of isocyanate groups have been removed from a polyisocyanate compound with an "m" number of isocyanate groups; Z represents a residue, which is the same or different from each other, after hydrogen atoms have been removed from active hydrogen-containing compounds that are capable of reacting with an isocyanate group, and at least two of the Z's are a pyrazole groups represented by the formula (II):{in the formula (II), n represents an integer of from 0 to 3; if n is 1 or higher, R1, which is the same or different from each other, represents an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, an aralkyl group having 7 to 12 carbon atoms, an N-substituted carbamyl group, a phenyl group, -NO2, a halogen atom, or -CO-O-R2 (in the formula, R2 is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms)}].
机译:本发明的拒水拒油剂组合物,其包含吡唑嵌段的疏水性多异氰酸酯和非离子型表面活性剂的水分散液,其中所述吡唑嵌段的疏水性多异氰酸酯含有下式(I)表示的吡唑嵌段的疏水性多异氰酸酯和非离子表面活性剂。提供具有6个碳原子或更少的全氟烷基的拒油剂组分:R(-NH-CO-Z) m (I)[在式(I)中,m表示2以上的整数; R表示从具有“ m”个异氰酸酯基的多异氰酸酯化合物中除去“ m”个异氰酸酯基后的残基。 Z表示从能够与异氰酸酯基反应的含活性氢的化合物中除去氢原子后的残基,彼此相同或不同,并且至少两个Z为由下式表示的吡唑基。公式(II): <图像文件=“ IMGA0001.GIF” he =“ 18” id =“ ia01” imgContent =“ chem” imgFormat =“ GIF” wi =“ 86” /> {在式(II)中,n表示0至3的整数; n为1以上时,彼此相同或不同的R 1 表示碳原子数1〜6的烷基,碳原子数2〜6的烯基,芳烷基。具有7至12个碳原子的基团,N-取代的氨基甲酰基,苯基,-NO 2 ,卤素原子或-CO-OR 2 (在式中,R 2 是氢原子或具有1-6个碳原子的烷基)}]。

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