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WATER-AND-OIL REPELLANT COMPOSITION FUNCTIONAL TEXTILE PRODUCT AND PRODUCTION METHOD FOR FUNCTIONAL TEXTILE PRODUCT

机译:水,油,臭组合物功能性纺织品产品及功能性纺织品产品的生产方法

摘要

The water and oil repellent composition of the present invention comprises a pyrazole block hydrophobic polyisocyanate aqueous dispersion containing a pyrazole block hydrophobic polyisocyanate represented by the following general formula (I) and a nonionic surfactant, and a foot having a perfluoroalkyl group having 6 or less carbon atoms Contains water and oil components. Formula I In the formula (I) m is an integer of 2 or more, R is a residue other than the m isocyanate groups from the polyisocyanate compound having m isocyanate groups, Z may be the same or different and is a residue other than a hydrogen atom from an active hydrogen-containing compound capable of reacting with an isocyanate group, and at least two of Z's are pyrazole groups represented by the following formula (II). (II) In the above formula (II) n is an integer of 0 to 3, and when n is 1 or more, R 1 may be the same or different and is an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, an aralkyl group having 7 to 12 carbon atoms, A carbamoyl group, a phenyl group, -NO 2 , a halogen atom or -CO-OR 2 (wherein R 2 is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms).
机译:本发明的拒水拒油组合物包括:吡唑嵌段疏水性多异氰酸酯水分散体,其含有下述通式(I)表示的吡唑嵌段疏水性多异氰酸酯和非离子表面活性剂;和具有碳原子数为6以下的全氟烷基的足。原子包含水和油成分。式(I)式(I)中,m为2以上的整数,R为具有m个异氰酸酯基的多异氰酸酯化合物中的m个异氰酸酯基以外的残基,Z可以相同或不同,为a以外的残基。能够与异氰酸酯基反应的含活泼氢的化合物的氢原子,Z中的至少两个为下式(II)表示的吡唑基。 (II)在上式(II)中,n是0至3的整数,并且当n为1以上时,R 1 可以相同或不同,并且是具有1至1的烷基。碳原子数为6,碳原子数为2至6的烯基,碳原子数为7至12的芳烷基,氨基甲酰基,苯基,-NO 2 ,卤素原子或-CO-或 2 (其中R 2 是氢原子或碳原子数为1至6的烷基)。

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