首页> 外国专利> WATER SPLITTING OXYGEN EVOLVING CATALYST, METHOD OF PREPARARING THE CATALYST, ELECTRODE HAVING THE CATALYST AND WATER SPLITTING OXYGEN EVOLVING DEVICE HAVING THE ELECTRODE

WATER SPLITTING OXYGEN EVOLVING CATALYST, METHOD OF PREPARARING THE CATALYST, ELECTRODE HAVING THE CATALYST AND WATER SPLITTING OXYGEN EVOLVING DEVICE HAVING THE ELECTRODE

机译:分解水制氧催化剂,制备方法,具有该电极的电极和具有该电极的分解水制氧装置

摘要

PURPOSE: A water splitting oxygen generating catalyst, a method for preparing the same, an electrode, and a device for generating water splitting oxygen are provided to increase the specific surface area of a water splitting oxygen generating catalyst by containing a flake-shaped metal oxide, thereby increasing the activity of the catalyst. CONSTITUTION: A water splitting oxygen generating catalyst is represented by chemical formula 1, Co1-xMxOy, and contains a flake-shaped metal oxide. In chemical formula 1, M is Al, In, Ga, Si, or Sn; and x and y satisfy inequations, 0=x0.5 and 1y2, respectively. The aspect ratio of the metal oxide is in the range of 50-500. The specific surface area of the metal oxide measured with an electrochemical method is in the range of 50-1000 m^2/g. A method for preparing a water splitting oxygen generating catalyst comprises the steps of: preparing one or more metal nitrate aqueous solutions (12); injecting the metal nitrate aqueous solutions into a 3-electrode cell (10) comprising a working electrode (WE0,WE1,WE2), a reference electrode (RE), and a counter electrode (CE); forming a metal hydroxide based on the metal nitrate aqueous solutions; electrochemically coating the metal hydroxide on the working electrode; and thermally treating the working electrode, and converting the metal hydroxide into a metal oxide.
机译:用途:提供了一种水分解氧产生催化剂,其制备方法,电极和用于产生水分解氧的设备,以通过包含片状金属氧化物来增加水分解氧产生催化剂的比表面积。从而增加了催化剂的活性。组成:水分解氧生成催化剂由化学式1 Co1-xMxOy表示,并包含片状金属氧化物。在化学式1中,M为Al,In,Ga,Si或Sn; x和y分别满足0≤x≤0.5和1≤y≤2的关系。金属氧化物的长径比在50-500的范围内。用电化学方法测量的金属氧化物的比表面积在50-1000m 2 / g的范围内。一种制备水分解产氧催化剂的方法,包括以下步骤:制备一种或多种金属硝酸盐水溶液(12);和将金属硝酸盐水溶液注入到包括工作电极(WE0,WE1,WE2),参比电极(RE)和对电极(CE)的3电极池(10)中;基于金属硝酸盐水溶液形成金属氢氧化物;将金属氢氧化物电化学涂覆在工作电极上;对所述工作电极进行热处理,将所述金属氢氧化物转化为金属氧化物。

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