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HYDROTHERMAL TREATMENT OF PHOSPHORUS-MODIFIED ZEOLITE CATALYSTS

机译:磷改性沸石催化剂的水热处理

摘要

treatment of ZSM-5 type zeolite catalyst has a silica / alumina molar ratio is greater than or equal to about 200 ZSM-5 zeolite is performed by treating the catalyst with a phosphorus compound . Is of the treated ZSM-5 zeolite catalyst is calcined and jeungyeol . Jeungyeol of the catalyst is carried out at a temperature of less than about 300 . Holds any other metal in addition to the phosphorus -treated ZSM-5 zeolite catalyst is provided from any treatment of the ZSM-5 zeolite with a compound containing other metal in addition to less than 0.05% by weight of the catalyst . These catalysts may be used in aromatic alkylation reactor by contacting under conditions suitable for aromatic alkylation catalyst in the reactor feed and the aromatic hydrocarbon and alkylating agent . May offer a joint supply of water to the reactor for aromatic alkylation water .
机译:硅/氧化铝摩尔比大于或等于200左右的ZSM-5型沸石催化剂的处理是通过用磷化合物处理来进行的。是将经过处理的ZSM-5沸石催化剂煅烧成正醇。催化剂的正醇在小于约300℃的温度下进行。除了用磷处理的ZSM-5沸石以外,还含有除0.05%(重量)以下催化剂以外的其他金属的化合物,可以对ZSM-5沸石进行除磷处理。这些催化剂可以通过在适合于反应器进料中的芳族烷基化催化剂的条件下与芳族烃和烷基化剂接触而用于芳族烷基化反应器中。可以向反应器联合供应水,用于芳香烷基化水。

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