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CATION-EXCHANGE DISPLACEMENT CHROMATOGRAPHY PROCESS AND CATIONIC ORGANIC COMPOUNDS FOR USE AS DISPLACER COMPOUNDS IN CATION-EXCHANGE DISPLACEMENT CHROMATOGRAPHY PROCESS
CATION-EXCHANGE DISPLACEMENT CHROMATOGRAPHY PROCESS AND CATIONIC ORGANIC COMPOUNDS FOR USE AS DISPLACER COMPOUNDS IN CATION-EXCHANGE DISPLACEMENT CHROMATOGRAPHY PROCESS
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机译:阳离子交换色谱法和用作阳离子交换色谱法中置换剂的阳离子有机化合物
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摘要
The present invention is used in a chromatographic process and the substitution process, the following general formula (I) display having Standing on the compound to be: ; Here, each group R 1 , R 2 , R 3 , R ' 1 , R ' 2 , and R' 3 is independently may be selected from alkyl, aryl and aralkyl, wherein the ring containing at least one quaternary nitrogen R 1 and R 2 , R 1 and R ' 1 , R 1 and R 4 , R 4 and R ' 4 , or R 4 and R 5 may be formed by any one or more of the ; Each R 4 , R ' 4 , R 5 , and R' 5 is independently alkyl, aryl , aralkyl and -(CH2)a-(CHY)b-(CH2)c-N+R1R2R3 An - can be chosen from, where R 1 , R 2 and R 3 is as defined above; Each Y is, independently, -H, -OH, -OR 6 , halo, alkyl, may be selected from aryl and aralkyl, wherein -R 6 is alkyl or -(CH2)a-(CHOH)b-(CH2)c-N+R1R2R3An- Number and, where R 1 , R 2 and R 3 is as defined above; Each q and z are independently 0 to about 6 may be of any integer, with the proviso that q + z is about 6 or less; Each of a, b and c may be any integer a is independently 0 to 2, the sum of a + b + c in any stage of the short side is at least 1; Each An -. may be independently selected from one or more desired organic or inorganic monovalent or polyvalent anion of a bar to obtain a neutral compound
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机译:本发明用于色谱法和取代法中,下列通式(I)显示在该化合物上的代表为:在此,每个组R 1 Sub>,R 2 Sub>,R 3 Sub>,R' 1 Sub>,R' 2 Sub>,且R' 3 Sub>独立地选自烷基,芳基和芳烷基,其中所述环含有至少一个季氮原子R 1 Sub>和R < Sub> 2 Sub>,R 1 Sub>和R' 1 Sub>,R 1 Sub>和R 4 Sub>,R 4 Sub>和R' 4 Sub>或R 4 Sub>和R 5 Sub>可以由一个或多个;每个R 4 Sub>,R' 4 Sub>,R 5 Sub>和R' 5 Sub>独立地为烷基,芳基,芳烷基和-(CH 2 Sub>) a Sub>-(CHY) b Sub>-(CH 2 Sub>) c < / Sub> -N + Sup> R 1 Sub> R 2 Sub> R 3 Sub> An - Sup>可以从以下选择:R 1 Sub>,R 2 Sub>和R 3 Sub>如上定义;每个Y独立地是-H,-OH,-OR 6 Sub>,卤素,烷基,可以选自芳基和芳烷基,其中-R 6 Sub>是烷基或- (CH 2 Sub>) a Sub>-(CHOH) b Sub>-(CH 2 Sub>) c Sub > -N + Sup> R 1 Sub> R 2 Sub> R 3 Sub> An - Sup>编号,并且其中,R 1 Sub>,R 2 Sub>和R 3 Sub>如上定义; q和z各自独立地为0至约6,可以是任何整数,条件是q + z为约6或更小; a,b和c中的每一个可以是任意的整数,a独立地为0至2,在短边的任何阶段中a + b + c的和至少为1;每个An -。 Sup>可以独立地选自一种或多种所需的有机或无机单价或多价阴离子,以获得中性化合物
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