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Composition containing lanthanum-perovskite on a substrate of aluminum or aluminum oxyhydroxide, METHOD FOR PRODUCING AND USE IN CATALYSIS

机译:在铝或羟基氧化铝上的含钙钛矿镧的组合物,制备方法和在催化中的用途

摘要

1. A composition comprising a perovskite of the formula LaMO, wherein M represents at least one element selected from iron, aluminum or manganese in the form of particles dispersed on a support based on aluminum oxide or oxyhydroxide, aluminum, characterized in that after calcination at 700 ° C for 4 hours perovskite is a crystallographically pure phase and perovskite particles have a size of not more than 15 nm.2. A composition according to claim 1, characterized in that the particles have a size of not more than 10 nm.3. A composition according to claim 1 or 2, characterized in that the amount of the perovskite in the composition is from 5% to 30%, more particularly from 10% to 20% by masse.4. A composition according to claim 1 or 2, characterized in that the perovskite of at least one element of La and M is partially substituted by at least one substitute elementom.5. A composition according to claim 4, characterized in that the replacement element selected from La and rare-earth elements calcium and substituting element M selected from cobalt or strontsiya.6. A composition according to claim 1 or 2, characterized in that the perovskite has a deficiency of elements or La M.7. A composition according to claim 1 or 2, characterized in that after calcination at 900 ° C for 4 hours perovskite particles have a size of not more than 18 nm, more particularly not more than 15 nm.8. A composition according to claim 1 or 2, characterized in that after calcination at 1000 ° C for 4 hours perovskite particles have a size of not more than 22 nm.9. A composition according to claim 7, characterized in that the perovskite is crystallographically pure fazoy.10. A composition according to claim 8, characterized in that the perovskite is crystallographically pure fazoy.11. A composition according to claim 1 or 2, characterized in that alumina or aluminum oxyhydroxide stabilized substrate
机译:1.一种组合物,其包含式LaMO的钙钛矿,其中M表示选自铁,铝或锰的至少一种元素,其为分散在基于氧化铝或羟基氧化物,铝的载体上的颗粒形式,其特征在于,在90℃下煅烧后700℃4小时钙钛矿为晶体纯相,钙钛矿颗粒尺寸不超过15 nm。2。 2.根据权利要求1的组合物,其特征在于颗粒的尺寸不大于10nm.3。 3.根据权利要求1或2所述的组合物,其特征在于,所述钙钛矿在所述组合物中的量为5质量%至30质量%,更特别地为10质量%至20质量%。 3.根据权利要求1或2所述的组合物,其特征在于,La和M中的至少一种元素的钙钛矿被至少一种替代元素部分取代。5。 5.根据权利要求4所述的组合物,其特征在于,选自La和稀土元素钙的置换元素和选自钴或锶的取代元素M。6。 3.根据权利要求1或2的组合物,其特征在于所述钙钛矿缺乏元素或La M.7。 3.根据权利要求1或2所述的组合物,其特征在于,在900℃下煅烧4小时后,钙钛矿颗粒的尺寸不大于18nm,更特别地不大于15nm。8。 3.根据权利要求1或2所述的组合物,其特征在于,在1000℃下煅烧4小时后,钙钛矿颗粒的尺寸不大于22nm。9。 8.根据权利要求7的组合物,其特征在于钙钛矿是晶体学纯的重氮唑。 9.根据权利要求8的组合物,其特征在于所述钙钛矿为晶体学纯的重氮。 3.根据权利要求1或2的组合物,其特征在于氧化铝或氢氧化铝
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