首页> 外国专利> By ring-opening cross metathesis of cyclooctene and acrylic acid (ROCM), dodeca-2,10-diene-1,12-production process of the dicarboxylic acid or 1,12-dodecane dicarboxylic acid

By ring-opening cross metathesis of cyclooctene and acrylic acid (ROCM), dodeca-2,10-diene-1,12-production process of the dicarboxylic acid or 1,12-dodecane dicarboxylic acid

机译:通过环辛烯和丙烯酸(ROCM)的开环交叉复分解反应,可以生产十二羧酸-2,10-二烯-1,12的二羧酸或1,12-十二烷二羧酸的生产方法

摘要

The invention relates to a method for producing 1,2-dodeca-2,10-diene diacid and 1,12-dodecanoic acid whereby cyclooctene and acrylic acid are reacted with a ruthenium catalyst by way of a metathesis reaction at high substrate concentrations until the reaction takes place in substance, the resulting unsaturated dicarboxylic acid being precipitated and being hydrated in a second reaction step.
机译:本发明涉及一种制备1,2-十二烷基-2,10-二烯二酸和1,12-十二烷酸的方法,其中环辛烯和丙烯酸通过复分解反应在高底物浓度下与钌催化剂反应,直至得到高浓度的底物。反应实质上进行,所得的不饱和二羧酸在第二反应步骤中沉淀并水合。

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