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Polymer transducer using paste and coating film as electrolyte membrane and electrode membrane

机译:使用糊剂和涂膜作为电解质膜和电极膜的聚合物换能器

摘要

[PROBLEMS] To provide a paste that can be adjusted to an arbitrary solid content concentration and excellent in handling property, coating property, and storage stability, and has a uniform and excellent flexibility by a few coating and drying processes. There are provided an electrolyte membrane / electrode membrane which is a coating film formed in a thickness of 5 mm and a polymer transducer which can be realized industrially and economically and which exhibits excellent performance. The paste includes a polymer block (a-1) containing a unit represented by the chemical formula (1) and a rubbery polymer block (a-2) substantially free of ionic groups at room temperature. A solid polymer electrolyte (A) comprising a block copolymer containing, an organic solvent (B) having a boiling point of 150 ° C. or higher, an insoluble in the organic solvent (B), a major axis of 1 to 100 μm and an aspect ratio of 5 The following non-dissociable particles (C) are contained. In the polymer transducer, either an electrolyte membrane or a pair of electrode membranes sandwiching the electrolyte membrane is formed by drying and solidifying this paste.
机译:[问题]提供一种糊剂,该糊剂可以调节至任意的固体含量浓度,并且具有优异的处理性能,涂覆性能和储存稳定性,并且通过少量的涂覆和干燥工序而具有均匀且优异的柔韧性。提供一种电解质膜/电极膜,其为形成为5mm的厚度的涂膜以及聚合物换能器,其可以工业上和经济上实现并且表现出优异的性能。该糊剂包括在室温下含有由化学式(1)表示的单元的聚合物嵌段(a-1)和基本上不含离子基团的橡胶状聚合物嵌段(a-2)。固体聚合物电解质(A),其包含嵌段共聚物,所述嵌段共聚物包含沸点为150℃或更高的有机溶剂(B),不溶于所述有机溶剂(B),长轴为1至100μm和长径比为5。含有以下的非离解性粒子(C)。在聚合物换能器中,通过干燥和固化该糊剂来形成电解质膜或将电解质膜夹在中间的一对电极膜。

著录项

  • 公开/公告号JPWO2012039425A1

    专利类型

  • 公开/公告日2014-02-03

    原文格式PDF

  • 申请/专利权人 株式会社クラレ;

    申请/专利号JP20120535053

  • 发明设计人 加藤 利典;高橋 活栄;山下 隆;

    申请日2011-09-21

  • 分类号C08L53;C09D153;C09D5/24;C09D7/12;C08K7;H01B1/22;H01B1/24;H01B1/06;H02N11;

  • 国家 JP

  • 入库时间 2022-08-21 16:10:43

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