ALDEHYDE-SELECTIVE WACKER-TYPE OXIDATION OF UNBIASED ALKENES

摘要

This disclosure is directed to methods of preparing organic aldehydes, each method comprising contacting a terminal olefin with an oxidizing mixture comprising:(a) a dichloro-palladium complex;(b) a copper complex;(c) a source of nitrite;under aerobic reaction conditions sufficient to convert at least a portion of the terminal olefin to an aldehyde.