A high-voltage lithium-ion battery cathode material includes LiNi0.5-xMn1.5MxO4 (0≦x≦0.2, M═Mg, Zn, Co. Cu, Fe, Ti, Zr, Ru, and Cr), which is coated with a coating material, which may be a carbon coating material, a metal phosphate coating material, or a combination thereof. The carbon coating material may be acetylene black, graphene oxide, conductive graphite, glucose, sucrose, starch, lactose, maltose, phenolic resins, polyvinyl alcohol, or a combination thereof, and the metal phosphate coating material may be FePO4, LiFePO4, CoPO4, Mn3(PO4)2, LnPO4. The coating material may account for 1 to 10% (wt %). Products of the present invention have high reversible capacities. Synthesis methods are disclosed that are simple and controllable, can produce uniform coating, and are suitable for industrial scale production.
展开▼
机译:高压锂离子电池正极材料包括LiNi 0.5-x Sub> Mn 1.5 Sub> M x Sub> O 4 Sub>( (0≤x≤0.2,M═Mg,Zn,Co,Cu,Fe,Ti,Zr,Ru和Cr)涂覆有涂层材料,该涂层材料可以是碳涂层材料,金属磷酸盐涂层材料,或其组合。碳涂层材料可以是乙炔黑,氧化石墨烯,导电石墨,葡萄糖,蔗糖,淀粉,乳糖,麦芽糖,酚醛树脂,聚乙烯醇或它们的组合,并且金属磷酸盐涂层材料可以是FePO 4。 / Sub>,LiFePO 4 Sub>,CoPO 4 Sub>,Mn 3 Sub>(PO 4 Sub>) 2 Sub>,LnPO 4 Sub>。涂料可占1至10%(重量%)。本发明的产品具有高可逆容量。公开了简单且可控制的合成方法,其可以产生均匀的涂层,并且适合于工业规模生产。
展开▼