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PHOSPHORUS-SILICON SYNERGISTIC FLAME RETARDANTS AND THE PREPARTION METHOD AND USE THEREOF

机译:磷硅增效阻燃剂及其制备方法和用途

摘要

The present invention discloses a phosphorus-silicon synergistic flame retardant and the preparation method and use thereof. The phosphorus-silicon synergistic flame retardant provided by the present invention has a structural general formula shown as formula I. A new type of compound containing phosphorus and silicon is prepared by the present invention using the cheap organic boron catalyst, and employing the addition reaction of diphenyl phosphine oxide and derivatives thereof with silicone containing carbon-carbon double bond. Such compounds have the properties of hydrolytic resistance, easy purification, and low synthesis cost, etc. Phosphorus and silicon elements in the molecular structures of such compounds both can act as the flame retardants solely, and meantime can work synergistically, thereby enduing the common polymeric materials with the excellent flame retardant property.; embedded image
机译:本发明公开了一种磷硅协同阻燃剂及其制备方法和用途。本发明提供的磷硅协同阻燃剂的结构通式如式I所示。本发明利用廉价的有机硼催化剂,通过加成反应制得了一种新型的含磷硅化合物。二苯基氧化膦及其衍生物与含碳-碳双键的有机硅。这类化合物具有耐水解,易纯化,合成成本低等特点。这些化合物分子结构中的磷和硅元素都可以单独作为阻燃剂,同时可以协同工作,从而使普通的聚合物具有优异阻燃性能的材料。 “嵌入式图像”

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