首页> 外国专利> The process of obtaining poly (acid lu00c1tico) using acid, 12 - tungstofosfu00d3rico supported on activated carbon as catalyst heterogu00caneo

The process of obtaining poly (acid lu00c1tico) using acid, 12 - tungstofosfu00d3rico supported on activated carbon as catalyst heterogu00caneo

机译:使用活性炭上负载的12-钨钨酸/多环十二烷酸作为催化剂杂多酸酯制取聚酸的过程

摘要

The process of obtaining poly (acid lu00c1tico) using acid, 12 - tungstofosfu00d3rico supported on activated carbon as catalyst heterogu00caneo. The present invention relates to a process for the production of poly (lactic acid) from the mixture racu00eamica D, L lactic acid using acid catalyst of br0nsted heterogeneous.More specifically, the present invention provides the production of poly - L - lactic acid by a polycondensation reaction facilitated by 12 - tungstofosfu00f3rico acid supported on activated carbon.This catalyst has some advantages compared to the conventional homogeneous catalysis can be recovered after the production process, and can be reused in a new cycle reaction via a simple thermal treatment on the solid acid.In addition, this catalyst is highly selective and estereoespecu00edfico for this type of polymerization without causing apparent by-products, using such a mixture racu00eamica as starting monomer, a fact which helps to decrease, in high degree, the cost of production of the polu00edme Ro.
机译:使用负载在活性炭上的12-钨酸,钨酸作为催化剂杂多酸酯,获得聚酸(酸l)的过程。本发明涉及一种使用布朗斯台德异质酸的酸催化剂从混合物D,L乳酸中制备聚乳酸的方法。更具体地说,本发明提供了聚-L-乳酸的制备方法。通过负载在活性炭上的12-钨磷 u3f3rico酸促进的缩聚反应,与传统的均相催化相比,该催化剂具有一些优势,可在生产过程后回收,并可通过简单的热处理在新的循环反应中重复使用另外,该催化剂对于这种类型的聚合反应具有高选择性和酯选择性,而不会产生明显的副产物,使用这种混合物racamicaamica作为起始单体,这一事实在很大程度上有助于降低,pol的生产成本。

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