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PROCESS FOR DECARBOXYLATING C-C BOND FORMATION

机译:对碳-碳键形成进行脱碳的过程

摘要

The invention relates to a method for decarboxylating C-C cross-linking by reacting carboxylic salts with carbon electrophiles in the presence of transition metal compounds as catalysts. The method represents a decarboxylating cross-coupling of carboxylic acid salts with carbon electrophiles, wherein the catalyst contains two transition metals and/or transition metal compounds, from which one is present, preferably, in the oxidation step, which are different from each other by one unit, and catalyses a radical decarboxylation which is absorbed during the second oxidation steps, which are different from each other by two units and catalyses the two electron processes of a cross-linking reaction.
机译:本发明涉及通过在过渡金属化合物作为催化剂的存在下使羧酸盐与碳亲电试剂反应来使C-C交联脱羧的方法。该方法代表了羧酸盐与碳亲电试剂的脱羧交叉偶联,其中催化剂包含两种过渡金属和/或过渡金属化合物,优选在氧化步骤中存在两种过渡金属和/或过渡金属化合物,它们彼此不同。一个单元,并催化在第二氧化步骤中被吸收的自由基脱羧,所述自由基脱羧彼此之间相差两个单元,并催化交联反应的两个电子过程。

著录项

  • 公开/公告号IN262397B

    专利类型

  • 公开/公告日2014-08-22

    原文格式PDF

  • 申请/专利权人

    申请/专利号IN8603/DELNP/2007

  • 发明设计人 LUKAS GOOSSEN;GUO-JUN DENG;

    申请日2007-11-07

  • 分类号C07C45/65;

  • 国家 IN

  • 入库时间 2022-08-21 15:57:12

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