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Process and adsorbent for removal of Pb (II) and Hg (II) ions from aqueous medium using thiol functionalized cobalt ferrite magnetic nanoparticles

机译:使用硫醇官能化的钴铁氧体磁性纳米颗粒从水性介质中去除Pb(II)和Hg(II)离子的方法和吸附剂

摘要

the invention belongs to the field of processes for the removal of ions from aqueous media, particularly for the removal of pb (ii), and hg (ii) ions from aqueous medium using magnetic nanoparticles tiolno funkcionaliziranih cobalt ferrite as well as an adsorbent prepared by this process.the process of pb (ii), and hg (ii) ions from aqueous medium using tiolno funkcionaliziranih cobalt ferrite magnetic nanoparticles, since in this.the surface modification of cobalt ferrite magnetic nanoparticles (cofe204) carried out by the combination of tetraetoksi silana (teos) and 3 - merkaptopropil trimetoksisilana (mptms) in different mnou017einskih ratios r = (h2o) / (teos) and p = (h2o) / (mptms) and the variation of process parametersthe reaction time in the range 1 hours to 24 hours, and the reaction temperature in the range from room temperature to 50 degrees c, in a manner that ensures that the adsorption of heavy metal ions (pb2 + and hg2 +) in the ph range between ph 3.5 and ph 8, the temperature range between 4 and 80 degrees c, a interv the alu between 15 min and 5dnem and mass adsorbenta between 4 and 40 mg.
机译:本发明属于使用磁性纳米粒子tiolno funkcionaliziranih钴铁氧体以及由吸附剂制备的吸附剂从水性介质中除去离子,特别是从水性介质中除去pb(ii)和hg(ii)离子的方法领域。该过程是使用Tiolno funkcionaliziranih钴铁氧体磁性纳米颗粒从水性介质中提取pb(ii)和hg(ii)离子的过程,因为在此过程中,通过四四氯化碳的组合对钴铁氧体磁性纳米颗粒(cofe204)进行了表面改性silana(teos)和3-巯基丙三酸酯三苯甲基锡兰(mptms)在不同的mno比率r =(h2o) /(teos)和p =(h2o) /(mptms)下以及反应参数的变化1小时至24小时,反应温度在室温至50摄氏度的范围内,以确保在ph值介于pH 3.5和ph 8之间吸附重金属离子(pb2 +和hg2 +) ,温度范围介于4到80摄氏度之间,间隔时间介于15分钟和5 dnem之间,质量吸附物介于4到40 mg之间。

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