首页> 外国专利> SPHERICAL NATERIAL COMPRISING METALLIC NANOPARTICLES TRAPPED IN A MESOSTRUCTURED OXIDE MATRIX AND USE THEREOF AS CATALYST IN HYDROCARBORN REFINING PROCESS

SPHERICAL NATERIAL COMPRISING METALLIC NANOPARTICLES TRAPPED IN A MESOSTRUCTURED OXIDE MATRIX AND USE THEREOF AS CATALYST IN HYDROCARBORN REFINING PROCESS

机译:球形分子,由金属纳米颗粒夹杂在介晶的氧化物基质中,并用作氢化物在烃精制过程中的催化剂

摘要

An inorganic material is described, constituted by at least two elementary spherical particles, each of said spherical particles comprising metallic nanoparticles having at least one band with a wave number in the range 750 to 1050 cm-1 in Raman spectroscopy and containing one or more metals selected from vanadium, niobium, tantalum, molybdenum and tungsten, said metallic nanoparticles being trapped in a mesostructured matrix based on an oxide of an element Y selected from silicon, aluminium, titanium, tungsten, zirconium, gallium, germanium, tin, antimony, lead, vanadium, iron, manganese, hafnium, niobium, tantalum, yttrium, cerium, gadolinium, europium and neodymium. Said matrix has pores with a diameter in the range 1.5 to 50 nm and amorphous walls with a thickness in the range 1 to 30 nm. Said elementary spherical particles have a maximum diameter of 200 microns and said metallic nanoparticles have a maximum dimension strictly less than 1 nm.
机译:描述了一种无机材料,其由至少两个基本球形颗粒组成,每个所述球形颗粒包含金属纳米颗粒,所述金属纳米颗粒在拉曼光谱中具有至少一个波数在750至1050cm-1范围内的谱带并且包含一种或多种金属。选自钒,铌,钽,钼和钨的所述金属纳米颗粒被捕获在基于选自硅,铝,钛,钨,锆,镓,锗,锡,锑,铅的元素Y的氧化物的介孔结构基质中,钒,铁,锰,ha,铌,钽,钇,铈,g 、,和钕。所述基质具有直径在1.5至50nm范围内的孔和厚度在1至30nm范围内的无定形壁。所述基本球形颗粒的最大直径为200微米,所述金属纳米颗粒的最大尺寸严格小于1nm。

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