Transportable formulations packaged organic peroxide safely comprising reactive phlegmatisers

摘要

A method for producing a polymer by a method of radical polymerization, wherein the played in 25% w / w of phlegmatiser that was used to flematizar peroxide or peroxides used as radical source libresen said method is reacted such that no can be extracted from the polymer by transporting aContainer containing peroxide formulation to the polymerization unit and introduction of its contents in procedure laid polymerization, said container having a greater than 1 liter and filled with size: - 90 to 1% w / w of one or more peroxides selected from the group consisting of: peroxyesters, incluyendoderivados peroxyester of ketone peroxides, peroxycarbonates, including derivatives peroxycarbonate deperóxidos ketone, diacyl peroxides with 1 to 48 carbon atoms, diperoxicetales, trioxepanes, peroxides dedialquilo , mixed peroxides containing two radicals different peroxygen-bearing a molecule and mezclasde two or more of these peroxides, - 10 to 99% w / w of one or more phlegmatizers with a flash point (junction) greater than 5 ° C and a deebullición point (junction) which is greater than 60 ° C greater than the decomposition temperature autoacceleration of laformulación peroxide, selected said phlegmatizer the group consisting of: 1-hexene, 1-heptene, 1-octene, 1-nonene, 1-decene, 1-undecene, 1 -dodeceno and mixtures thereof. - 0-75% w / w of selected hydrocarbons and hydrocarbons oxigenadoshasta a total of 100% optional conventional phlegmatisers.