首页> 外国专利> BIFUNCTIONAL COMPOUNDS CARBAMOYL/PHOSPHONIC ACID OR PHOSPHONATE USED AS LIGANDS FOR URANIUM(VI), THEIR SYNTHESIS PROCESSES AND THEIR USES USES

BIFUNCTIONAL COMPOUNDS CARBAMOYL/PHOSPHONIC ACID OR PHOSPHONATE USED AS LIGANDS FOR URANIUM(VI), THEIR SYNTHESIS PROCESSES AND THEIR USES USES

机译:用作铀(VI)的化合物的氨基甲酸酯/膦酸或磷酸盐双官能化合物及其合成方法和用途

摘要

The invention relates to novel compounds which have the general formula (I): Formula (I), wherein: m = 0, 1 or 2; R1 and R2 = a hydrocarbon group, linear or branched, C6 to C12; R3 = H, a linear or branched C1-C12 hydrocarbon group optionally comprising one or more heteroatoms; a C3-C8 monocyclic hydrocarbon group, optionally comprising one or more heteroatoms, or a monocyclic (hetero) aryl group; or R2 and R3 together form a - (CH2) n- group with n = 1 to 4; R4 = a linear or branched C2-C8 hydrocarbon group or a monocyclic aromatic group; R5 = H or a hydrocarbon group, linear or branched, C1 to C12. The invention also relates to processes for synthesizing these compounds and to the use of said compounds as ligands for uranium (VI) and, in particular for extracting uranium (VI) from an aqueous solution of 'Phosphoric acid.
机译:本发明涉及具有通式(I)的新型化合物:式(I),其中:m = 0、1或2; m = 0、1或2。 R1和R2 = C6-C12的直链或支链的烃基; R3 = H,直链或支链的C1-C12烃基,其任选地包含一个或多个杂原子; C3-C8单环烃基,其任选包含一个或多个杂原子,或单环(杂)芳基;或R 2和R 3一起形成-(CH 2)n-基团,其中n = 1-4。 R4 =直链或支链的C2-C8烃基或单环芳族基团; R5 = H或C1-C12的直链或支链烃基。本发明还涉及合成这些化合物的方法,并且涉及所述化合物作为铀(VI)的配体的用途,尤其涉及从磷酸水溶液中提取铀(VI)的用途。

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