首页> 外国专利> BIFUNCTIONAL COMPOUNDS CARBAMOYL/PHOSPHONIC ACID OR PHOSPHONATE USED AS LIGANDS FOR URANIUM(VI), THEIR SYNTHESIS PROCESSES AND THEIR USES USES

BIFUNCTIONAL COMPOUNDS CARBAMOYL/PHOSPHONIC ACID OR PHOSPHONATE USED AS LIGANDS FOR URANIUM(VI), THEIR SYNTHESIS PROCESSES AND THEIR USES USES

机译:用作铀(VI)的化合物的氨基甲酸酯/膦酸或磷酸盐双官能化合物及其合成方法和用途

摘要

The invention relates to new compounds which correspond to the general formula (I): (see formula I) in which: m = 0, 1 or 2; R1 and R2 = a linear or branched C6 to C12 hydrocarbon group; R3 = H, a linear or branched C1 to C12 hydrocarbon group, optionally comprising one or more heteroatoms; a C3 to C8 monocyclic hydrocarbon group, optionally comprising one or more heteroatoms, or a monocyclic (hetero) aryl group; or R2 and R3 together form a - (CH2) n- group with n = from 1 to 4; R4 = a hydrocarbon group, linear or branched, C2 to C8, or a monocyclic aromatic group; R5 = H or a hydrocarbon group, linear or branched, C1 to C12. The invention also relates to processes for the synthesis of these compounds as well as to the use of said compounds as ligands for uranium (VI) and, in particular for extracting uranium (VI) from an aqueous solution of uranium (VI). 'Phosphoric acid.
机译:本发明涉及对应于通式(I)的新化合物:(参见式I)其中m = 0、1或2; m = 0、1或2。 R1和R2 =直链或支链的C6至C12烃基; R3 = H,C1-C12的直链或支链烃基,任选地包含一个或多个杂原子; C3至C8的单环烃基,任选地包含一个或多个杂原子,或单环(杂)芳基;或R 2和R 3一起形成-(CH 2)n-基团,其中n = 1-4。 R4 =直链或支链的烃基,C2至C8,或单环芳族基团; R5 = H或C1-C12的直链或支链烃基。本发明还涉及这些化合物的合成方法以及所述化合物作为铀(VI)的配体的用途,特别是涉及从铀(VI)的水溶液中提取铀(VI)的用途。 '磷酸。

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