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Modified molecular sieve with high selectivity to ammonia nitrogen in waste water and preparation method thereof

机译:对废水中氨氮选择性高的改性分子筛及其制备方法

摘要

A modified molecular sieve with high selectivity to ammonia nitrogen in waste water is provided. The main structure of the modified molecular sieve comprises: (1) a molecular sieve as a basic skeleton, and (2) functional materials loaded on the inner surface of the skeleton, wherein the functional materials are magnesium compound and phosphorus compound. The method for preparing the modified molecular sieve comprises the following steps: (1) dissolving magnesium salt into water to form a magnesium salt solution; (2) dissolving phosphoric acid into water to form a phosphoric acid solution; (3) adding the molecular sieve into the magnesium salt solution, followed by stirring, standing, drying, and baking; and (4) adding the baked modified molecular sieve loaded with magnesium compound into the phosphoric acid solution, followed by stirring, standing, drying, and baking. The modified molecular sieve can effectively solve the problem of generating large pressure drop when a fixed bed reactor is utilized as the way to treat waste water containing ammonia nitrogen, and can remove ammonia nitrogen in waste water with high selectively.
机译:提供了一种对废水中的氨氮具有高选择性的改性分子筛。改性分子筛的主要结构包括:(1)作为基本骨架的分子筛;(2)负载在骨架内表面上的功能材料,其中功能材料为镁化合物和磷化合物。所述改性分子筛的制备方法包括以下步骤:(1)将镁盐溶解于水中形成镁盐溶液; (2)将磷酸溶解在水中形成磷酸溶液; (3)将分子筛加入镁盐溶液中,搅拌,静置,干燥,烘烤; (4)在磷酸溶液中加入经焙烧的载有镁化合物的改性分子筛,搅拌,静置,干燥,焙烧。本发明的改性分子筛可以有效解决将固定床反应器作为处理含氨氮废水的方法时产生较大压降的问题,并可以选择性地高去除废水中的氨氮。

著录项

  • 公开/公告号AU2010350932B2

    专利类型

  • 公开/公告日2014-04-17

    原文格式PDF

  • 申请/专利权人 NANJING UNIVERSITY;

    申请/专利号AU20100350932

  • 发明设计人 REN HONGQIANG;ZHANG TAO;DING LILI;

    申请日2010-12-16

  • 分类号B01J20/18;B01J20/30;C02F1/28;C02F1/58;C02F101/16;

  • 国家 AU

  • 入库时间 2022-08-21 15:53:26

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