首页> 外国专利> METHOD FOR THE HYDRODESULFURIZATION OF A GASOLINE FRACTION IN THE PRESENCE OF A SUPPORTED SULFIDE CATALYST PREPARED USING AT LEAST ONE CYCLIC OLIGOSACCHARIDE

METHOD FOR THE HYDRODESULFURIZATION OF A GASOLINE FRACTION IN THE PRESENCE OF A SUPPORTED SULFIDE CATALYST PREPARED USING AT LEAST ONE CYCLIC OLIGOSACCHARIDE

机译:有至少一种环寡糖制备的支撑硫化物催化剂存在下汽油馏分的加氢脱硫方法

摘要

The invention relates to a method for the hydrodesulfurization of a gasoline fraction containing hydrocarbons having at least two carbon atoms per molecule and having a final boiling point of no higher than 250°C, wherein the method comprises contacting the gasoline fraction with at least one catalyst, the active phase of which includes at least one Group VIII metal and at least one Group VIB metal deposited on a substrate, said catalyst being prepared according to a method including at least: i) a step of contacting at least said substrate with at least one solution containing at least one precursor of at least said Group VIII metal and at least one precursor of at least said Group VIB metal; ii) a step of contacting at least said substrate with at least one organic compound comprising at least one cyclic oligosaccharide consisting of at least six glucopyranose subunits bonded at α-(1,4); iii); a drying step for obtaining at least said Group VIII metal and at least said Group VIB metal in oxide form; and then iv) a sulfurization step in order to obtain the active phase in sulfide form, wherein steps i) and ii) can be carried out separately in any order, or simultaneously.
机译:本发明涉及一种汽油馏分的加氢脱硫的方法,该汽油馏分包含每个分子具有至少两个碳原子并且最终沸点不高于250℃的烃,其中该方法包括使汽油馏分与至少一种催化剂接触。 ,其活性相包括至少一种沉积在基材上的VIII族金属和至少一种VIB族金属,所述催化剂是根据至少包括以下方法的方法制备的:i)使至少所述基材与至少一种接触的步骤。一种溶液,其包含至少一种至少一种所述VIII族金属的前体和至少一种至少一种所述VIB族金属的前体; ii)使至少所述底物与至少一种有机化合物接触的步骤,所述至少一种有机化合物包含至少一种环状低聚糖,所述环状低聚糖由至少六个在α-(1,4)键合的吡喃葡萄糖亚基组成; iii);干燥步骤,用于获得至少所述第VIII族金属和至少所述VIB族金属的氧化物形式;然后iv)进行硫化步骤以获得硫化物形式的活性相,其中步骤i)和ii)可以以任何顺序分别进行或同时进行。

著录项

  • 公开/公告号EP2598611B1

    专利类型

  • 公开/公告日2014-04-30

    原文格式PDF

  • 申请/专利权人 IFP ENERGIES NOUVELLES;

    申请/专利号EP20110743260

  • 发明设计人 DIEHL FABRICE;DEVERS ELODIE;

    申请日2011-06-24

  • 分类号C10G45/08;C10G45/10;B01J23/85;B01J27/185;B01J27/19;B01J31/02;B01J31/22;B01J37/02;C07C1/32;

  • 国家 EP

  • 入库时间 2022-08-21 15:48:38

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